Ketone transfer hydrogenation reactions catalyzed by a phosphinite ruthenium PCP complex The X-ray crystal structure of [C6H4-1,3-(OPPh2{Ru(η6-p-cymene)Cl2})2]
作者： Ricardo Cerón-Camacho , Valente Gómez-Benítez , Ronan Le Lagadec , David Morales-Morales , Rubén A. Toscano
DOI: 10.1016/J.MOLCATA.2005.11.041
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摘要: The reaction of the potentially tridentate phosphinite PCP pincer type ligand [C 6 H 4 -1,3-(OPPh 2 ) ] with [( η - p -cymene)RuCl affords bimetallic species {Ru( -cymene)Cl }) ]. Several attempts, including change ruthenium starting material (e.g. -benzene)RuCl and reflux conditions to achieve coordination diphosphinite in a fashion failed. Complex was tested transfer hydrogenation ketones.
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