Discharge-ionization of metals on an indifferent electrode: Part I. Theoretical analysis
作者： Kh.Z. Brainina , A.M. Il'in , G.V. Jarunina , L.I. Roitman
DOI: 10.1016/S0022-0728(79)80406-4
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摘要: A mathematical model is proposed for describing metal discharge-ionization processes involving interaction with electrode surface. Use made of the concept two energetic states deposited on surface, differing by magnitude Gibb's free energy (ΔG0). Calculated values are given electrochemical equivalents in first (q1) and second (q2) as a function ΔG0, potential, duration deposition, concentration discharging ions. It shown that conditions governing cathode process determine character stripping polarogram (one or current peaks), linear correlation exists between difference peak potentials value energy.
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