Sideronatrite: A mineral with a {Fe2(SO4)4(OH)2} guildite type chain?

作者: F. Scordari

DOI: 10.1007/BF01081857

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摘要: Recently several natural and artificial ferric iron sulphate crystal structures have been solved. Sideronatrite, Na2Fe3+(SO4)2(OH)·3H2O, does not provide good crystals for structural purposes. However if we examine crystallographic, chemical physical data some useful information about the ...Fe−O−S... topology can be inferred. In fact this analysis strengthens hypothesis that there is a {Fe 2 3+ (SO4)4(OH)2} chain in sideronatrite like found guildite, Cu2+Fe3+(SO4)2(OH)·4H2O.

参考文章(10)
F. Scordari, Fibroferrite: A mineral with a {Fe(OH) (H2O)2SO4} spiral chain and its relationship to Fe(OH)SO4, butlerite and parabutlerite TMPM Tschermaks Mineralogische und Petrographische Mitteilungen. ,vol. 28, pp. 17- 29 ,(1981) , 10.1007/BF01081848
P. Süsse, The crystal structure of amarantite, Fe2(SO4)2O · 7H2O Zeitschrift Fur Kristallographie. ,vol. 127, pp. 261- 275 ,(1968) , 10.1524/ZKRI.1968.127.1-4.261
T. Araki, P. B. Moore, Overite, segelerite, and jahnsite: a study in combinatorial polymorphism American Mineralogist. ,vol. 62, pp. 692- 702 ,(1977)
Che'ng Wan, Subrata Ghose, George R. Rossman, Guildite, a layer structure with a ferric hydroxy-sulphate chain and its optical absorption spectra Mineralogical Society of America. ,(1978)
Paul D. Robinson, J. H. Fang, Crystal structures and mineral chemistry of hydrated ferric sulphates: II. The crystal structure of paracoquimbite American Mineralogist. ,vol. 55, pp. 1534- 1540 ,(1970)
Jacques Borène, Structure cristalline de la parabutlérite Bulletin de la Société française de Minéralogie et de Cristallographie. ,vol. 93, pp. 185- 189 ,(1970) , 10.3406/BULMI.1970.6452
K. Mereiter, Die Kristallstruktur des Ferrinatrits, Na 3 Fe[SO 4 ] 3 · 3H 2 O TMPM Tschermaks Mineralogische und Petrographische Mitteilungen. ,vol. 23, pp. 317- 327 ,(1976) , 10.1007/BF01083106
K. Mereiter, Die Kristallstruktur des Ferrinatrits, Na3Fe[SO4]3 � 3H2O TMPM Tschermaks Mineralogische und Petrographische Mitteilungen. ,vol. 23, pp. 317- 327 ,(1976) , 10.1007/BF01083106