Selectively Adsorptive Extraction of Phenylarsonic Acids in Chicken Tissue by Carboxymethyl α-Cyclodextrin Immobilized Fe3O4 Magnetic Nanoparticles Followed Ultra Performance Liquid Chromatography Coupled Tandem Mass Spectrometry Detection
作者： Jing Jia , Wei Zhang , Jing Wang , Peilong Wang , Ruohua Zhu
DOI: 10.1371/JOURNAL.PONE.0107147
关键词:
摘要: Carboxymethyl α-cyclodextrin immobilized Fe3O4 magnetic nanoparticles (CM-α-CD-Fe3O4) were synthesized for the selectively adsorptive extraction of five phenylarsonic acids including p-amino acid, p-nitro p-hydroxy p-acylamino acid and p-hydroxy-3-nitro in chicken tissue. Using ultra performance liquid chromatography coupled with tandem mass spectrometry (UPLC-MS/MS), a highly sensitive analytical method was proposed determination acids. It shown that CM-α-CD-Fe3O4 could extract complex tissue samples high efficiency. Under optimal conditions, enrichment factor, ranging from 349 to 606 fold, obtained. The limits detection (LODs) (at signal-to-noise ratio 3) range 0.05–0.11 µg/kg applied target muscle liver samples. Recoveries spiked 0.2 µg/kg, 2.0 20 each 77.2%–110.2%, relative standard deviation (RSD) less than 12.5%.
harvard.edu
paperity.org参考文章(35)
P. J. Craig, Organometallic Compounds in the Environment ,(2002)
Doris Kuehnelt, Walter Goessler, Organoarsenic Compounds in the Terrestrial Environment John Wiley & Sons, Ltd. pp. 223- 275 ,(2003) , 10.1002/0470867868.CH6
Aaron R. Roerdink, Joseph H. Aldstadt, Sensitive method for the determination of roxarsone using solid-phase microextraction with multi-detector gas chromatography. Journal of Chromatography A. ,vol. 1057, pp. 177- 183 ,(2004) , 10.1016/J.CHROMA.2004.09.071
Rui Xue Li, Shu Mei Liu, Jian Qing Zhao, Hideyuki Otsuka, Atsushi Takahara, None, Preparation and characterization of cross-linked β-cyclodextrin polymer/Fe3O4 composite nanoparticles with core-shell structures Chinese Chemical Letters. ,vol. 22, pp. 217- 220 ,(2011) , 10.1016/J.CCLET.2010.09.014
Wan-Ru Chen, Ching-Hua Huang, Surface adsorption of organoarsenic roxarsone and arsanilic acid on iron and aluminum oxides. Journal of Hazardous Materials. ,vol. 227, pp. 378- 385 ,(2012) , 10.1016/J.JHAZMAT.2012.05.078
S. L. Chen, S. J. Yeh, M. H. Yang, T. H. Lin, Trace element concentration and arsenic speciation in the well water of a Taiwan area with endemic Blackfoot disease Biological Trace Element Research. ,vol. 48, pp. 263- 274 ,(1995) , 10.1007/BF02789408
A.Z.M. Badruddoza, Goh Si Si Hazel, K. Hidajat, M.S. Uddin, Synthesis of carboxymethyl-β-cyclodextrin conjugated magnetic nano-adsorbent for removal of methylene blue Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 367, pp. 85- 95 ,(2010) , 10.1016/J.COLSURFA.2010.06.018
Pingjing Li, Bin Hu, Sensitive determination of phenylarsenic compounds based on a dual preconcentration method with capillary electrophoresis/UV detection Journal of Chromatography A. ,vol. 1218, pp. 4779- 4787 ,(2011) , 10.1016/J.CHROMA.2011.05.058
Asem A. Atia, Ahmed M. Donia, Saeda A. El‐Enein, Ahmed M. Yousif, Effect of Chain Length of Aliphatic Amines Immobilized on a Magnetic Glycidyl Methacrylate Resin towards the Uptake Behavior of Hg(II) from Aqueous Solutions Separation Science and Technology. ,vol. 42, pp. 403- 420 ,(2007) , 10.1080/01496390601069978
Gautam Samanta, Tarit Roy Chowdhury, Badal K. Mandal, Bhajan K. Biswas, Uttam K. Chowdhury, Gautam K. Basu, Chitta R. Chanda, Dilip Lodh, Dipankar Chakraborti, Flow Injection Hydride Generation Atomic Absorption Spectrometry for Determination of Arsenic in Water and Biological Samples from Arsenic-Affected Districts of West Bengal, India, and Bangladesh☆ Microchemical Journal. ,vol. 62, pp. 174- 191 ,(1999) , 10.1006/MCHJ.1999.1713