Defect-rich ZnO nanosheets of high surface area as an efficient visible-light photocatalyst

作者: Jing Wang , Yi Xia , Yan Dong , Ruosong Chen , Lan Xiang

DOI: 10.1016/J.APCATB.2016.03.040

关键词:

摘要: A facile ultra-rapid solution method was developed to fabricate ZnO nanosheets with tunable BET surface area and rich oxygen-vacancy defects. The addition of 1 mol L− 1 Na 2 SO 4 led to an increase of BET surface area of ZnO nanosheets from 6.7 to 34.5 m 2/g, through an electrostatic-controlled growth and self-assembly mechanism. Detailed analysis based on Raman scattering, room-temperature photoluminescence, X-ray photoelectron spectroscopy and electron spin resonance revealed that the as-prepared ZnO nanosheets were rich in …

参考文章(50)
Ü Özgür, Ya I Alivov, Chunli Liu, A Teke, MA Reshchikov, S Doğan, V Avrutin, S-J Cho, H Morkoc, None, A comprehensive review of ZnO materials and devices Journal of Applied Physics. ,vol. 98, pp. 041301- ,(2005) , 10.1063/1.1992666
Soumita Mukhopadhyay, Partha Pratim Das, Suvendu Maity, Prasanta Ghosh, P. Sujatha Devi, Solution grown ZnO rods: Synthesis, characterization and defect mediated photocatalytic activity Applied Catalysis B-environmental. ,vol. 165, pp. 128- 138 ,(2015) , 10.1016/J.APCATB.2014.09.045
Yuanhui Zheng, Chongqi Chen, Yingying Zhan, Xingyi Lin, Qi Zheng, Kemei Wei, Jiefang Zhu, Yingjie Zhu, Luminescence and Photocatalytic Activity of ZnO Nanocrystals: Correlation between Structure and Property Inorganic Chemistry. ,vol. 46, pp. 6675- 6682 ,(2007) , 10.1021/IC062394M
Konstantinos Kotsis, Volker Staemmler, Ab initio calculations of the O1s XPS spectra of ZnO and Zn oxo compounds Physical Chemistry Chemical Physics. ,vol. 8, pp. 1490- 1498 ,(2006) , 10.1039/B515699H
Ekemena Oghenovoh Oseghe, Suresh Maddila, Patrick Gathura Ndungu, Sreekanth Babu Jonnalagadda, Effect of surfactant concentration on active species generation and photocatalytic properties of TiO2 Applied Catalysis B-environmental. ,vol. 176, pp. 288- 297 ,(2015) , 10.1016/J.APCATB.2015.04.010
Fengping Peng, Qiang Zhou, Dunpu Zhang, Chunhua Lu, Yaru Ni, Jiahui Kou, Jian Wang, Zhongzi Xu, Bio-inspired design: Inner-motile multifunctional ZnO/CdS heterostructures magnetically actuated artificial cilia film for photocatalytic hydrogen evolution Applied Catalysis B-environmental. ,vol. 165, pp. 419- 427 ,(2015) , 10.1016/J.APCATB.2014.09.050
Isao Nakamura, Nobuaki Negishi, Shuzo Kutsuna, Tatsuhiko Ihara, Shinichi Sugihara, Koji Takeuchi, Role of oxygen vacancy in the plasma-treated TiO2 photocatalyst with visible light activity for NO removal Journal of Molecular Catalysis A-chemical. ,vol. 161, pp. 205- 212 ,(2000) , 10.1016/S1381-1169(00)00362-9
Mohammad Abbas Mahmood, Sunandan Baruah, Joydeep Dutta, None, Enhanced visible light photocatalysis by manganese doping or rapid crystallization with ZnO nanoparticles Materials Chemistry and Physics. ,vol. 130, pp. 531- 535 ,(2011) , 10.1016/J.MATCHEMPHYS.2011.07.018
Yongchun Lu, Yanhong Lin, Dejun Wang, Lingling Wang, Tengfeng Xie, Tengfei Jiang, A high performance cobalt-doped ZnO visible light photocatalyst and its photogenerated charge transfer properties Nano Research. ,vol. 4, pp. 1144- 1152 ,(2011) , 10.1007/S12274-011-0163-4
Xiaoyan Qin, Xiaoyang Zhang, Ying Dai, Junpeng Wang, Zeyan Wang, Baibiao Huang, Yandong Ma, Yuanyuan Liu, Oxygen vacancy induced band-gap narrowing and enhanced visible light photocatalytic activity of ZnO. ACS Applied Materials & Interfaces. ,vol. 4, pp. 4024- 4030 ,(2012) , 10.1021/AM300835P