Iron phosphate glass containing simulated fast reactor waste: Characterization and comparison with pristine iron phosphate glass
作者： Kitheri Joseph , R. Asuvathraman , R. Venkata Krishnan , T.R. Ravindran , R. Govindaraj
DOI: 10.1016/J.JNUCMAT.2014.05.038
关键词:
摘要: Abstract Detailed characterization was carried out on an iron phosphate glass waste form containing 20 wt.% of a simulated nuclear waste. High temperature viscosity measurement by the rotating spindle method. The Fe 3+ /Fe ratio and structure this loaded investigated using Mossbauer Raman spectroscopy respectively. Specific heat in range 300–700 K differential scanning calorimeter. Isoconversional kinetic analysis employed to understand crystallization behavior glass. forming ability stability were also evaluated. All measured properties compared with characteristics pristine
harvard.edu
sci-hub.se 参考文章(35)
Kitheri Joseph, R. Venkata Krishnan, K.V. Govindan Kutty, P.R. Vasudeva Rao, Kinetics of nonisothermal crystallization of Cs2O–Fe2O3–P2O5 glasses Thermochimica Acta. ,vol. 512, pp. 67- 70 ,(2011) , 10.1016/J.TCA.2010.09.001
James E Shelby, Introduction to Glass Science and Technology ,(2020)
L.-M. Martinez, C. A. Angell, A thermodynamic connection to the fragility of glass-forming liquids Nature. ,vol. 410, pp. 663- 667 ,(2001) , 10.1038/35070517
P.A. Bingham, R.J. Hand, O.M. Hannant, S.D. Forder, S.H. Kilcoyne, Effects of modifier additions on the thermal properties, chemical durability, oxidation state and structure of iron phosphate glasses Journal of Non-crystalline Solids. ,vol. 355, pp. 1526- 1538 ,(2009) , 10.1016/J.JNONCRYSOL.2009.03.008
D.R. Uhlmann, A kinetic treatment of glass formation Journal of Non-crystalline Solids. ,vol. 7, pp. 337- 348 ,(1972) , 10.1016/0022-3093(72)90269-4
A Moguš-Milanković, A Gajović, A Šantić, D.E Day, Structure of sodium phosphate glasses containing Al2O3 and/or Fe2O3. Part I Journal of Non-crystalline Solids. ,vol. 289, pp. 204- 213 ,(2001) , 10.1016/S0022-3093(01)00701-3
Kitheri Joseph, Sajal Ghosh, K.V. Govindan Kutty, P.R. Vasudeva Rao, Crystallization kinetics, stability and glass forming ability of iron phosphate and cesium loaded iron phosphate glasses Journal of Nuclear Materials. ,vol. 426, pp. 233- 239 ,(2012) , 10.1016/J.JNUCMAT.2012.03.048
Wenhai Huang, Delbert E. Day, Chandra S. Ray, Cheol-Woon Kim, Andrea Mogus-Milankovic, Vitrification of high chrome oxide nuclear waste in iron phosphate glasses Journal of Nuclear Materials. ,vol. 327, pp. 46- 57 ,(2004) , 10.1016/J.JNUCMAT.2004.01.021
A Moguš-Milanković, A Šantić, A Gajović, D.E Day, Spectroscopic investigation of MoO3–Fe2O3–P2O5 and SrO–Fe2O3–P2O5 glasses. Part I Journal of Non-crystalline Solids. ,vol. 325, pp. 76- 84 ,(2003) , 10.1016/S0022-3093(03)00362-4
Richard K Brow, Review: the structure of simple phosphate glasses Journal of Non-crystalline Solids. ,vol. 263, pp. 1- 28 ,(2000) , 10.1016/S0022-3093(99)00620-1