XPS Study of the Surface Composition of a Catalytic System: Iron Promoted by Potassium and Aluminum Oxides

作者: B. N. Kuznetsov , V. M. Perov , A. M. Alekseev , V. I. Yakerson

DOI: 10.1023/A:1004809014917

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摘要: The surface composition of a model catalyst for ammonia synthesis based on iron promoted with aluminum and potassium oxides was investigated by X-ray photoelectron spectroscopy. studied in oxidized, passivated, reduced states. redistribution components the is course reduction hydrogen overheating at 700°C. It shown that 4–6-mn thick layer enriched promoters (K Al) impurities (Si), while concentration low. Promotion makes more resistant to overheating.

参考文章(9)
Wayne E. Morgan, John R. Van Wazer, Wojciech J. Stec, Inner-orbital photoelectron spectroscopy of the alkali metal halides, perchlorates, phosphates, and pyrophosphates Journal of the American Chemical Society. ,vol. 95, pp. 751- 755 ,(1973) , 10.1021/JA00784A018
B. N. Kuznetsov, V. M. Perov, A. M. Alekseyev, D. L. Astanovsky, V. I. Yakerson, Change in carbon content on the surface of a multicomponent catalyst during its reduction, oxidation and due to action of the reaction medium Reaction Kinetics and Catalysis Letters. ,vol. 67, pp. 89- 93 ,(1999) , 10.1007/BF02475832
C. D. Wagner, Factors affecting quantitative determinations by x-ray photoelectron spectroscopy Analytical Chemistry. ,vol. 49, pp. 1282- 1290 ,(1977) , 10.1021/AC50017A003
DC Silverman, M Boudart, Surface composition of promoted iron catalysts Journal of Catalysis. ,vol. 77, pp. 208- 220 ,(1982) , 10.1016/0021-9517(82)90161-0
Tery L. Barr, An ESCA study of the termination of the passivation of elemental metals The Journal of Physical Chemistry. ,vol. 82, pp. 1801- 1810 ,(1978) , 10.1021/J100505A006
B. N. Kuznetsov, V. M. Petrov, A. M. Alekseev, V. I. Yakerson, Valence state of active elements on the surface of a multicomponent catalyst under the action of reaction medium Reaction Kinetics and Catalysis Letters. ,vol. 63, pp. 329- 333 ,(1998) , 10.1007/BF02475407