Infrared Spectroscopy and Structure of (NO)n Clusters
作者： Hiromichi Hoshina , Mikhail Slipchenko , Kirill Prozument , Deepak Verma , Michael W. Schmidt
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摘要: Nitrogen oxide clusters (NO)n have been studied in He droplets via infrared depletion spectroscopy and by quantum chemical calculations. The ν1 ν5 bands of cis-ON-NO dimer observed at 1868.2 1786.5 cm–1, respectively. Furthermore, spectral the trimer tetramer located vicinity corresponding accord with computed frequencies that place NO-stretch dimer, trimer, within a few wavenumbers each other. In addition, new line 1878.1 cm–1 close to band origin single molecules was assigned van der Waals bound dimers (NO)2, which are stabilized due rapid cooling droplets. Spectra larger (n > 5), broad unresolved features bands. Experiments calculations indicate trimers consist loosely third molecule, whereas consists two weakly dimers.
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David H. Magers, Huang Qiong, Jerzy Leszczyński, Singlet Nitric Oxide Dimer Revisited: An Unexpected High Stability Isomer Structural Chemistry. ,vol. 13, pp. 165- 172 ,(2002) , 10.1023/A:1015760600315
Hiromichi Hoshina, Dmitri Skvortsov, Mikhail N. Slipchenko, Boris G. Sartakov, Andrey F. Vilesov, Rotation of methane molecules in dimers and small clusters Journal of Chemical Physics. ,vol. 143, pp. 084305- 084305 ,(2015) , 10.1063/1.4928694
A. Benidar, R. Georges, R. Le Doucen, J. Boissoles, S. Hamon, A. Canosa, B.R. Rowe, Uniform Supersonic Expansion for FTIR Absorption Spectroscopy: The ν5 Band of (NO)2 at 26 K Journal of Molecular Spectroscopy. ,vol. 199, pp. 92- 99 ,(2000) , 10.1006/JMSP.1999.7986
Jong Keun Park, Hosung Sun, Relative stabilities of (NO)2 Chemical Physics. ,vol. 263, pp. 61- 68 ,(2001) , 10.1016/S0301-0104(00)00350-5
Elisabeth A. Wade, Joseph I. Cline, K. Thomas Lorenz, Carl Hayden, David W. Chandler, Direct measurement of the binding energy of the NO dimer The Journal of Chemical Physics. ,vol. 116, pp. 4755- 4757 ,(2002) , 10.1063/1.1459702
Anders Snis, Itai Panas, N2O2, N2O2- and N2O22-: structures, energetics and N-N bonding Chemical Physics. ,vol. 221, pp. 1- 10 ,(1997) , 10.1016/S0301-0104(97)00165-1
Motoi Tobita, S. Ajith Perera, Monika Musial, Rodney J. Bartlett, Marcel Nooijen, Jae Shin Lee, Critical comparison of single-reference and multireference coupled-cluster methods: Geometry, harmonic frequencies, and excitation energies of N2O2 Journal of Chemical Physics. ,vol. 119, pp. 10713- 10723 ,(2003) , 10.1063/1.1619952
A.R.W. McKellar, J.K.G. Watson, The Far Infrared Spectrum of the NO Dimer Journal of Molecular Spectroscopy. ,vol. 194, pp. 229- 235 ,(1999) , 10.1006/JMSP.1998.7798
M. Y. Choi, G. E. Douberly, T. M. Falconer, W. K. Lewis, C. M. Lindsay, J. M. Merritt, P. L. Stiles, R. E. Miller, Infrared spectroscopy of helium nanodroplets: novel methods for physics and chemistry International Reviews in Physical Chemistry. ,vol. 25, pp. 15- 75 ,(2006) , 10.1080/01442350600625092
Pierre Asselin, Pascale Soulard, Nelly Lacome, The NO Dimer: Jet-Cooled Study of ν1and ν5Transitions Journal of Molecular Spectroscopy. ,vol. 190, pp. 274- 277 ,(1998) , 10.1006/JMSP.1998.7580