An Efficient Synthesis of Novel Fused Cycloheptatrienes through Mn(II)-Mediated Formal Intermolecular [2 + 2 + 2 + 1] Cycloaddition
作者： Wen-Ming Shu , Jun-Rui Ma , Yan Yang , An-Xin Wu
DOI: 10.1021/OL500202Q
关键词:
摘要: A new method for manganous acetate tetrahydrate mediated formal intermolecular [2 + 2 1] cycloaddition was developed the synthesis of fused cycloheptatriene derivatives from N-(acylmethyl)pyridinium iodides and naphthoquinone. This provides an innovative route efficient convenient construction seven-membered carbocycles simple starting materials.
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