Vinyl alcohol copolymers containing allylamine functionality

作者: Ta-Wang Lai , Lawrence K. Wempe , Robert K. Pinschmidt

DOI:

关键词:

摘要: A modified poly(vinyl alcohol) copolymer is provided containing copolymerized units of allylamine and/or diallylamine by copolymerizing a vinyl ester, such as acetate, and an N-allylamide N,N-diallylamide, N-allylformamide N,N-diallylformamide hydrolyzing first the ester groups to hydroxy then amide amine groups. The second hydrolysis carried out on solvent-swollen particulate polymer slurried in acidic or basic medium. can contain small amounts unhydrolyzed addition functionality which characterizes copolymer.

参考文章(10)
Lawrence J. Guilbault, M. Fred Hoover, Polymeric amine conditioning additives for hair care products ,(1981)
Norbert Sendhoff, Michael Kroener, Primoz Lorencak, Friedrich Linhart, Werner Auhorn, Walter Denzinger, Heinrich Hartmann, Production of paper, board and cardboard ,(1991)
Daniel J. Dawson, Phillip J. Brock, Base hydrolysis of pendant amide polymers ,(1981)
Robert W. Stackman, Richard H. Summerville, Synthesis of N-vinylacetamide and preparation of some polymers and copolymers Industrial & Engineering Chemistry Product Research and Development. ,vol. 24, pp. 242- 246 ,(1985) , 10.1021/I300018A014
Michael Kroener, Friedrich Linhart, Fritz Brunnmueller, Rolf Schneider, Hans Mueller, Linear basic polymers, their preparation and their use ,(1982)
Price John A, Schuller Walter H, Copolymers of a bis ethylenically unsaturated amine ,(1956)