Kinetics of copyrolysis of coal with polyamide 6

作者: P. Straka , J. Náhunková , Z. Brožová

DOI: 10.1016/S0165-2370(03)00089-5

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摘要: Abstract Kinetics of thermal reactions coal with polyamide 6 by TGA and DSC methods was studied overall kinetic parameters were measured. In the range about 350–500 °C degradation proceeds, gas tar are evolved. Simultaneously, decomposition occurs e-caprolactam other products formed. The formation is promoted water hydrogen from degradation. Due to high content hydrogen, acts as a strong H-donor. Because significant component waste polyamides mixtures plastics, treatment tested during copyrolysis in stationary bed up final temperature 900 °C at heating rate 5 °C min −1 . It found that beside mainly carbon oxides, methane, aliphatic hydrocarbons, simple aromatics stable oil formed copyrolysis. yields tar/oil higher comparison those pyrolysis alone.

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