Proton magnetic resonance spectra of vinyl-metallic compounds
作者： D.J. Blears , S. Cawley , S.S. Danyluk
DOI: 10.1016/S0022-2852(68)80066-9
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摘要: A study has been made of the effects solvents and concentration on chemical shifts coupling constants α -chlorovinyltrichlorosilane ( -CTS) -chlorovinyltrimethylsilane -CTMS). The vinyl protons show a marked dependence in hydrogen-bonding benzene, particularly case -CTS. These shift changes are interpreted terms solute-solvent solute-solute interactions. Equilibrium have deduced, from data, for complexing reactions -CTS with various self-association cyclohexane. solvent geminal proton constant was observed most pronounced induced electron density bonding orbitals.
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