Effect of antisymmetric C–H stretching excitation on the dynamics of O(1D) + CH4 → OH + CH3
作者： Huilin Pan , Jiayue Yang , Dong Zhang , Quan Shuai , Dongxu Dai
DOI: 10.1063/1.4871135
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摘要: The effect of antisymmetric C–H stretching excitation CH4 on the dynamics and reactivity O(1D) + → OH CD3 reaction at collision energy 6.10 kcal/mol has been investigated using crossed-beam time-sliced velocity map imaging techniques. mode excited molecule was prepared by direct infrared excitation. From measured images CH3 products with laser off, product translational angular distributions were derived for both ground vibrationally reactions. Experimental results show that vibrational reagent is channeled exclusively into co-products and, hence, from excited-state are about one quantum hotter than those ground-state reaction, barely affected reagent. reac...
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