A Thermoreversible Supramolecular Polyurethane with Excellent Healing Ability at 45 °C

作者: Antonio Feula , Alexander Pethybridge , Ioannis Giannakopoulos , Xuegang Tang , Ann Chippindale

DOI: 10.1021/ACS.MACROMOL.5B01162

关键词:

摘要: We report the synthesis and characterization of a healable, elastomeric shape recovery supramolecular polyurethane whose properties result from self-complementary π–π stacking hydrogen bonding interactions plus phase separation. ESEM analysis photographic images have revealed that this material can heal at 45 °C in 15 min to recover mechanical pristine with healing efficiencies >99%. This is also able an applied strain 25% within 5 release load.

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