Motional dynamics in liquid 1,2,3,4-tetrahydro-5,6-dimethyl-1,4-methanonaphthalene

摘要: The rotational motion of molecules about the three space axes in liquid state can be described by diffusion tensor. Until recently most investigations concerning motions liquids employing dipolar spin-lattice relaxation data have proceeded on assumption that orientation tensor principal axis system coincides with intertial But this is not necessarily case for which consist rotating as asymmetrictop rotors less than two mutually perpendicular mirror planes. Usually it assumed that, hydrocarbons, a rotation systems respect to each other does occur because their weak intermolecular interactions. In order examine statement behaviour hydrocarbon 1,2,3,4-tetrahydro-5,6-dimethyl-1,4-methanonaphthalene (1) was investigated using 13C time measurements. orienta...