Controllable formation of heterotrimetallic coordination compounds: Systematically incorporating lanthanide and alkali metal ions into the manganese 12-metallacrown-4 framework
作者： Michael R. Azar , Thaddeus T. Boron , Jacob C. Lutter , Connor I. Daly , Kelcie A. Zegalia
DOI: 10.1021/IC402865P
关键词:
摘要: The inclusion of LnIII ions into the 12-MC-4 framework generates first heterotrimetallic complexes this molecular class. controllable and deliberate preparations these compounds are demonstrated through 12 crystal structures LnIIIMI(OAc)4[12-MCMnIII(N)shi-4](H2O)4·6DMF complex, where OAc– is acetate, shi3- salicylhydroximate, DMF N,N-dimethylformamide. Compounds 1–12 have MI as NaI, can be PrIII (1), NdIII (2), SmIII (3), EuIII (4), GdIII (5), TbIII (6), DyIII (7), HoIII (8), ErIII (9), TmIII (10), YbIII (11), YIII (12). An example with = KI also reported (DyIIIK(OAc)4[12-MCMnIII(N)shi-4](DMF)4·DMF (14)). When LaIII, CeIII, or LuIII used to prepare LnIIINaI(OAc)4[12-MCMnIII(N)shi-4] compound Na2(OAc)2[12-MCMnIII(N)shi-4](DMF)6·2DMF·1.60H2O (13) results. For 1–12, identity ion affects 12-MCMnIII(N)shi-4 largest LnIII, PrIII, causes an expansion 12...
acs.org
sci-hub.se 参考文章(104)
Xiao-Juan Zhao, Qing-Fu Zhang, Da-Cheng Li, Jian-Min Dou, Da-Qi Wang, Syntheses, structural characterizations and properties of 12-MC-4 organotin(IV) metallacrowns: [12-MCRSn(IV)N(shi)-4] and [12-MCRSn(IV)N(Clshi)-4] (R = Et, Bu, Ph; H3shi = salicylhydroxamic acid; H3Clshi = 5-chlorosalicylhydroxamic acid) Journal of Organometallic Chemistry. ,vol. 695, pp. 2134- 2141 ,(2010) , 10.1016/J.JORGANCHEM.2010.05.027
Marius Andruh, Isabelle Ramade, Epiphane Codjovi, Olivier Guillou, Olivier Kahn, Jean Christian Trombe, Crystal structure and magnetic properties of [Ln2Cu4] hexanuclear clusters (where Ln = trivalent lanthanide). Mechanism of the gadolinium(III)-copper(II) magnetic interaction Journal of the American Chemical Society. ,vol. 115, pp. 1822- 1829 ,(1993) , 10.1021/JA00058A029
Konstantis F. Konidaris, Vlasoula Bekiari, Eugenia Katsoulakou, Catherine P. Raptopoulou, Vassilis Psycharis, Evy Manessi-Zoupa, George E. Kostakis, Spyros P. Perlepes, Investigation of the zinc(II)–benzoate–2-pyridinealdoxime reaction system Dalton Transactions. ,vol. 41, pp. 3797- 3806 ,(2012) , 10.1039/C2DT11853J
Gellert Mezei, Jeff W. Kampf, Shilie Pan, Kenneth R. Poeppelmeier, Byron Watkins, Vincent L. Pecoraro, Metallacrown-based compartments: selective encapsulation of three isonicotinate anions in non-centrosymmetric solids Chemical Communications. pp. 1148- 1150 ,(2007) , 10.1039/B614024F
I. Tsivikas, M. Alexiou, A. A. Pantazaki, C. Dendrinou-Samara, D. A. Kyriakidis, D. P. Kessissoglou, The effect of fused 12-membered nickel metallacrowns on DNA and their antibacterial activity. Bioinorganic Chemistry and Applications. ,vol. 1, pp. 85- 97 ,(2003) , 10.1155/S1565363303000074
Murad A. AlDamen, Salvador Cardona-Serra, Juan M. Clemente-Juan, Eugenio Coronado, Alejandro Gaita-Ariño, Carlos Martí-Gastaldo, Fernando Luis, Oscar Montero, Mononuclear Lanthanide Single Molecule Magnets Based on the Polyoxometalates [Ln(W5O18)2]9− and [Ln(β2-SiW11O39)2]13−(LnIII = Tb, Dy, Ho, Er, Tm, and Yb) Inorganic Chemistry. ,vol. 48, pp. 3467- 3479 ,(2009) , 10.1021/IC801630Z
Sébastien Rochat, Zacharias Grote, Kay Severin, Ruthenium-based metallacrown complexes for the selective detection of lithium ions in water and in serum by fluorescence spectroscopy Organic and Biomolecular Chemistry. ,vol. 7, pp. 1147- 1153 ,(2009) , 10.1039/B820592B
Choong-Sun Lim, Jeff W. Kampf, Vincent L. Pecoraro, Establishing the binding affinity of organic carboxylates to 15-metallacrown-5 complexes. Inorganic Chemistry. ,vol. 48, pp. 5224- 5233 ,(2009) , 10.1021/IC9001829
A. J. L. Pombeiro. 117. D.S. Nesterov, V.N. Kokozay, V.V. Dyakonenko, O.V. Shishkin, J. Jezierska, A. Ozarowski, A.M. Kirillov, M.N. Kopylovich, An unprecedented heterotrimetallic Fe/Cu/Co core for mild and highly efficient catalytic oxidation of cycloalkanes by hydrogen peroxide Chemical Communications. pp. 4605- 4607 ,(2006) , 10.1039/B608790F
Agata Trzesowska, Rafal Kruszynski, Tadeusz J. Bartczak, New bond-valence parameters for lanthanides Acta Crystallographica Section B-structural Science. ,vol. 60, pp. 174- 178 ,(2004) , 10.1107/S0108768104002678