A study of vibrational excitations of HCN in the framework of an algebraic model

摘要: The vibrational description of the hydrogen cyanide molecule is presented in framework U(2) × U(3) × U(2) algebraic model. In our approach Hamiltonian first written configuration space, and thereafter expressed an form by introducing a realization coordinates momenta terms familiar bosonic operators for harmonic oscillator. An anharmonization procedure then applied to Hamiltonian, which consists replacing new set belonging su(2) algebra stretches su(3) bends. This equivalent starting interacting Morse oscillators stretching degrees freedom, without any analog with method obtaining representation provides natural connection between spectroscopic parameters structure force constants. analysis exci...