Preparation of chelating fibrous polymer by different diamines and study on their physical and chemical properties
作者： P. Tahaei , M. Abdouss , M. Edrissi , A. M. Shoushtari , M. Zargaran
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摘要: The present work describes a new modification process for producing chelating ion-exchanger fibers with distinct selectivity toxic heavy metal ions. Acrylic were reacted different diamine compounds in similar conditions. Modified acrylic prepared by partial conversion of the nitrile groups into amino under two-step processes. In first step, pure liquid was mixed and second water gradually added to reaction flask reach predetermined 3M concentration at refluxing temperature 91 °C. aminated (AAFs) used as an ion adsorbent series batch adsorption experiments removal chromium(III) lead (II) ions. Experimental results showed that modified fiber tetra methylene (TMD) has highest Pb(II) capacity. Results also ethylene (EDA) most Cr(III) ability. Solubility tests showed, amination treatments give rise intermolecular crosslinkage all samples. Freundlich Langmuir models simulated equilibrium data ions on their constants determined.
sci-hub.se 参考文章(14)
Dong Hun Shin, Young Gun Ko, Ung Su Choi, Woo Nyon Kim, Design of High Efficiency Chelate Fibers with an Amine Group To Remove Heavy Metal Ions and pH-Related FT-IR Analysis Industrial & Engineering Chemistry Research. ,vol. 43, pp. 2060- 2066 ,(2004) , 10.1021/IE030696F
Shubo Deng, Bai, J. Paul Chen, Aminated polyacrylonitrile fibers for lead and copper removal Langmuir. ,vol. 19, pp. 5058- 5064 ,(2003) , 10.1021/LA034061X
Shubo Deng, Renbi Bai, Removal of trivalent and hexavalent chromium with aminated polyacrylonitrile fibers: performance and mechanisms. Water Research. ,vol. 38, pp. 2424- 2432 ,(2004) , 10.1016/J.WATRES.2004.02.024
Susan T. Beatty, Robert J. Fischer, Dana L. Hagers, Edward Rosenberg, A comparative study of the removal of heavy metal ions from water using a silica-polyamine composite and a polystyrene chelator resin Industrial & Engineering Chemistry Research. ,vol. 38, pp. 4402- 4408 ,(1999) , 10.1021/IE9903386
Soo-Jin Park, Yu-Sin Jang, Jae-Woon Shim, Seung-Kon Ryu, Studies on pore structures and surface functional groups of pitch-based activated carbon fibers. Journal of Colloid and Interface Science. ,vol. 260, pp. 259- 264 ,(2003) , 10.1016/S0021-9797(02)00081-4
James Economy, Lourdes Dominguez, Christian L. Mangun, Polymeric ion exchange fibers Industrial & Engineering Chemistry Research. ,vol. 41, pp. 6436- 6442 ,(2000) , 10.1021/IE0204641
A.A. Shunkevich, Z.I. Akulich, G.V. Mediak, V.S. Soldatov, Acid-base properties of ion exchangers. III: Anion exchangers on the basis of polyacrylonitrile fiber Reactive & Functional Polymers. ,vol. 63, pp. 27- 34 ,(2005) , 10.1016/J.REACTFUNCTPOLYM.2005.02.002
B. Nasernejad, T. Esslam Zadeh, B. Bonakdar Pour, M. Esmaail Bygi, A. Zamani, Camparison for biosorption modeling of heavy metals (Cr (III), Cu (II), Zn (II)) adsorption from wastewater by carrot residues Process Biochemistry. ,vol. 40, pp. 1319- 1322 ,(2005) , 10.1016/J.PROCBIO.2004.06.010
V.V Ishtchenko, R.F Vitkovskaya, K.D Huddersman, Investigation of the mechanical and physico-chemical properties of a modified PAN fibrous catalyst Applied Catalysis A-general. ,vol. 242, pp. 221- 231 ,(2003) , 10.1016/S0926-860X(02)00512-4
Akihiko Nakano, Yuji Minoura, Non-catalysed polymerization of acrylamide Polymer. ,vol. 10, pp. 1- 10 ,(1969) , 10.1016/0032-3861(69)90002-0