摘要: At an electrified interface the double-layer problem plays a key role. Its characteristics for ionic liquids are discussed on basis of recent experimental and theoretical investigations contrasted with classical GCS model aqueous electrolytes. Emphasis this chapter is 2D 3D electrochemical phase formation growth at liquid/electrode studied by in situ scanning probe methods. The concept underpotential (UPD) deposition briefly introduced example Ag UPD Au(111) different behaviour liquid electrolytes described. Phenomena surface alloying underlying spinodal mechanism treated more detail. characteristic structures their evolution during Zn − Cd presented. Nanoscale metal semiconductor clusters from topic last section. Selected examples Al electrodeposition Si(111):H, Ni, Fe nanocrystal growth; Co bulk alloying; AlSb ZnSb compound deposition. ends thickness induced metal–nonmetal transition ultrathin Ge films electrodeposited or Si(111):H.
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springerlink.com参考文章(62)
Electrodeposition from Ionic Liquids Wiley-VCH Verlag GmbH & Co. KGaA. ,(2008) , 10.1002/9783527622917
Alain Karma, Nikolay Dimitrov, Karl Sieradzki, Jonah Erlebacher, Michael J. Aziz, Evolution of nanoporosity in dealloying Nature. ,vol. 410, pp. 450- 453 ,(2001) , 10.1038/35068529
Steven Baldelli, Probing Electric Fields at the Ionic Liquid-Electrode Interface Using Sum Frequency Generation Spectroscopy and Electrochemistry Journal of Physical Chemistry B. ,vol. 109, pp. 13049- 13051 ,(2005) , 10.1021/JP052913R
J. Ilja Siepmann, Michiel Sprik, Influence of surface topology and electrostatic potential on water/electrode systems Journal of Chemical Physics. ,vol. 102, pp. 511- 524 ,(1995) , 10.1063/1.469429
K Itaya, STM studies of solid/liquid interfaces Nanotechnology. ,vol. 3, pp. 185- 187 ,(1992) , 10.1088/0957-4484/3/4/007
Chun Hsien Chen, Scott M. Vesecky, Andrew A. Gewirth, In Situ Atomic Force Microscopy of Underpotential Deposition of Ag on Au(111) Journal of the American Chemical Society. ,vol. 114, pp. 451- 458 ,(1992) , 10.1021/JA00028A009
C.L. Aravinda, B. Burger, W. Freyland, Nanoscale electrodeposition of Al on n-Si(111): H from an ionic liquid Chemical Physics Letters. ,vol. 434, pp. 271- 275 ,(2007) , 10.1016/J.CPLETT.2006.12.012
A. Popov, N. Dimitrov, D. Kashchiev, T. Vitanov, E. Budevski, A model of the structural transformation processes in lead adsorbate on Ag(111) faces at low coverages Electrochimica Acta. ,vol. 34, pp. 269- 271 ,(1989) , 10.1016/0013-4686(89)87096-3
A.D. Graves, D. Inman, The electrical double layer in molten salts: Part 2. The double-layer capacitance Journal of Electroanalytical Chemistry. ,vol. 25, pp. 357- 372 ,(1970) , 10.1016/S0022-0728(70)80098-5
D. Borissov, C. L. Aravinda, W. Freyland, Comparative Investigation of Underpotential Deposition of Ag from Aqueous and Ionic Electrolytes: An Electrochemical and In Situ STM Study Journal of Physical Chemistry B. ,vol. 109, pp. 11606- 11615 ,(2005) , 10.1021/JP0443106