Siliconnitrogen bond formation by nucleophilic activation of siliconhydrogen bonds

作者: R.J.P. Corriu , D. Leclercq , P.H. Mutin , J.M. Planeix , A. Vioux

DOI: 10.1016/0022-328X(91)83192-7

关键词:

摘要: Abstract A method of forming SiN bonds by dehydro-coupling SiH and NH in the presence a nucleophilic catalyst is reported. The useful for preparation silylamines silazanes crosslinking organometallics polymers.

参考文章(8)
Yigal D. Blum, Kenneth B. Schwartz, Richard M. Laine, Preceramic Polymer Pyrolysis. I. Pyrolytic Properties of Polysilazanes. Journal of Materials Science. ,vol. 24, pp. 1707- 1718 ,(1989) , 10.1007/BF01105695
K J Wynne, R W Rice, Ceramics Via Polymer Pyrolysisdagger Annual Review of Materials Science. ,vol. 14, pp. 297- 334 ,(1984) , 10.1146/ANNUREV.MS.14.080184.001501
Claude Biran, Yigal D. Blum, Robert Glaser, Doris S. Tse, Kay A. Youngdahl, Richard M. Laine, Catalytic Synthesis of Oligosilazanes. 2 Journal of Molecular Catalysis. ,vol. 48, pp. 183- 197 ,(1988) , 10.1016/0304-5102(88)85004-1
Leo H. Sommer, Joel D. Citron, Group VIII metal-catalyzed reactions of organosilicon hydrides with amines, hydrogen halides, and hydrogen sulfide Journal of Organic Chemistry. ,vol. 32, pp. 2470- 2472 ,(1967) , 10.1021/JO01283A025
Reaoch R S, Lim T F, Legrow G E, Jonathan Lipowitz, Ceramics from hydridopolysilazane. American Ceramic Society Bulletin. ,vol. 66, pp. 363- 367 ,(1987)
Dietmar Seyferth, Gary H. Wiseman, Christian Prud'homme, A Liquid Silazane Precursor To Silicon Nitride Journal of the American Ceramic Society. ,vol. 66, ,(1983) , 10.1111/J.1151-2916.1983.TB09979.X
J. Boyer, C. Breliere, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, Enhancement of SiH bond reactivity in pentacoordinated structures Journal of Organometallic Chemistry. ,vol. 311, ,(1986) , 10.1016/0022-328X(86)80263-7