Molecular weight-enlarged ligands for asymmetric, homogeneously soluble hydrogenation catalysts, process for the production thereof and use

作者: Andreas Bommarius , Jens Woeltinger , Hans Henniges , Andreas Karau , Hans-Peter Krimmer

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摘要: A molecular weight-enlarged, homogeneously soluble ligand, useful in catalysts, particularly for the synthesis of enantiomerically enriched organic compounds, includes: a weight average at least 1000 g/mol; weight-enlarging polymer; optionally, polymer linker; and one homochiral active center; wherein center is bound to through linker or directly polymer.

参考文章(44)
Kenneth Gene Moloy, Emilio E. Bunel, Patrick Michael Burke, Joe Douglas Druliner, Leo Ernest Manzer, Manxue Wang, Hydroformylation of olefins using supported bis(phosphorus) ligands ,(1999)
Dean Alan Markley, Richard Earl Felter, Epoxy-phosphate ceramic compositions and methods of preparation ,(1986)
Juliane Beliczey, Guido Giffels, Udo Kragl, Christian Wandrey, Novel ligands derived from S-tyrosine for the enantioselective addition of diethylzinc to aldehydes Tetrahedron-asymmetry. ,vol. 8, pp. 1529- 1530 ,(1997) , 10.1016/S0957-4166(97)00150-X
Manfred T. Reetz, Gunther Lohmer, Renate Schwickardi, Synthese und katalytische Wirkung von dendritischen Diphosphan-Metallkomplexen Angewandte Chemie. ,vol. 109, pp. 1559- 1562 ,(1997) , 10.1002/ANGE.19971091331
Dennis J. Gravert, Kim D. Janda, Organic Synthesis on Soluble Polymer Supports: Liquid-Phase Methodologies. Chemical Reviews. ,vol. 97, pp. 489- 510 ,(1997) , 10.1021/CR960064L