Polyethylenimine modified magnetic graphene oxide nanocomposites for Cu2+ removal

作者: Ning Sui , Lina Wang , Xiaohan Wu , Xinghua Li , Jing Sui

DOI: 10.1039/C4RA11669K

关键词:

摘要: Fe3O4 nanoparticles were synthesized on graphene oxide (GO), then mixed with polyethylenimine to obtain GO/Fe3O4/PEI nanocomposites. Due the high surface area of GO, superparamagnetism Fe3O4, and excellent complex ability PEI, nanocomposites showed extremely Cu2+ removal efficiency. The capacity was 157 mg g−1, which is higher than most reported results. adsorption kinetics could be best described by a pseudo-second-order model. Moreover, easily recycled magnetic separation. After five cycles, efficiency remained 84%.

参考文章(44)
Thayyath Sreenivasan Anirudhan, Sreenivasan Rijith, Glutaraldehyde cross-linked epoxyaminated chitosan as an adsorbent for the removal and recovery of copper(II) from aqueous media Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 351, pp. 52- 59 ,(2009) , 10.1016/J.COLSURFA.2009.09.034
Lunhong Ai, Chunying Zhang, Zhonglan Chen, Removal of methylene blue from aqueous solution by a solvothermal-synthesized graphene/magnetite composite. Journal of Hazardous Materials. ,vol. 192, pp. 1515- 1524 ,(2011) , 10.1016/J.JHAZMAT.2011.06.068
Humera Jabeen, Vimlesh Chandra, Sehoon Jung, Jung Woo Lee, Kwang S. Kim, Seung Bin Kim, Enhanced Cr(VI) removal using iron nanoparticle decorated graphene Nanoscale. ,vol. 3, pp. 3583- 3585 ,(2011) , 10.1039/C1NR10549C
Jie Li, Shouwei Zhang, Changlun Chen, Guixia Zhao, Xin Yang, Jiaxing Li, Xiangke Wang, Removal of Cu(II) and fulvic acid by graphene oxide nanosheets decorated with Fe3O4 nanoparticles. ACS Applied Materials & Interfaces. ,vol. 4, pp. 4991- 5000 ,(2012) , 10.1021/AM301358B
Lili Wang, Lian Gao, Morphology-Controlled Synthesis and Magnetic Property of Pseudocubic Iron Oxide Nanoparticles Journal of Physical Chemistry C. ,vol. 113, pp. 15914- 15920 ,(2009) , 10.1021/JP9051243
Ashraf Shafaei, Farzin Zokaee Ashtiani, Tahereh Kaghazchi, Equilibrium studies of the sorption of Hg(II) ions onto chitosan Chemical Engineering Journal. ,vol. 133, pp. 311- 316 ,(2007) , 10.1016/J.CEJ.2007.02.016
Wei Li, Fei Wang, Shanshan Feng, Jinxiu Wang, Zhenkun Sun, Bin Li, Yuhui Li, Jianping Yang, Ahmed A. Elzatahry, Yongyao Xia, Dongyuan Zhao, Sol–Gel Design Strategy for Ultradispersed TiO2 Nanoparticles on Graphene for High-Performance Lithium Ion Batteries Journal of the American Chemical Society. ,vol. 135, pp. 18300- 18303 ,(2013) , 10.1021/JA4100723
Jiahong Wang, Shourong Zheng, Yun Shao, Jingliang Liu, Zhaoyi Xu, Dongqiang Zhu, Amino-functionalized Fe3O4@SiO2 core–shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal Journal of Colloid and Interface Science. ,vol. 349, pp. 293- 299 ,(2010) , 10.1016/J.JCIS.2010.05.010
Zacaria Reddad, Claire Gerente, Yves Andres, Pierre Le Cloirec, Adsorption of several metal ions onto a low-cost biosorbent: kinetic and equilibrium studies. Environmental Science & Technology. ,vol. 36, pp. 2067- 2073 ,(2002) , 10.1021/ES0102989
Xiaoming Sun, Zhuang Liu, Kevin Welsher, Joshua Tucker Robinson, Andrew Goodwin, Sasa Zaric, Hongjie Dai, None, Nano-Graphene Oxide for Cellular Imaging and Drug Delivery. Nano Research. ,vol. 1, pp. 203- 212 ,(2008) , 10.1007/S12274-008-8021-8