A zeroth order random network model of liquid water

摘要: A random network model is used to generate the oxygen–oxygen pair correlation function of liquid water and amorphous solid water. The basically an extension bent hydrogen bond proposed by Pople in 1951; it differs from earlier work that instead being a parametric fit data, predicts dispersion OO distances for each shell neighbors, OOO angles, independent spectroscopic data. Our based on hypothesis there exists separation time scales various classes molecular motion In particular we assert useful regard libration hindered translation as occurring quasistatic bonded molecules diffusion related relaxation processes much more slowly. predicted good but not perfect agreement with experiment over wide temperature range. As further test predict dielectr...