Electromechanical properties of poly(vinylidene-fluoride-chlorotrifluoroethylene) copolymer

作者: Zhimin Li , Yuhong Wang , Z.-Y. Cheng

DOI: 10.1063/1.2170425

关键词:

摘要: The electromechanical response of poly(vinylidene-fluoride-chlorotrifluoroethylene) [P(VDF-CTFE)] copolymers with 9 mol % (CT9) and 12 CTFE (CT12) is reported. CT12 (at room temperature) exhibits an electrostrictive strain more than 5% a piezoelectric constant d33 140pC∕N at dc bias 70MV∕m. It found that about 70% crystalline regions in P(VDF-CTFE) the nonpolar phase CT9 has crystallinity 25% higher CT12. difference performance between cannot be completely explained using structure/conformation change alone. believed contribution interfacial layers to polarization plays important role.

参考文章(22)
Ron Pelrine, Roy Kornbluh, Qibing Pei, Jose Joseph, High-speed electrically actuated elastomers with strain greater than 100% Science. ,vol. 287, pp. 836- 839 ,(2000) , 10.1126/SCIENCE.287.5454.836
Haisheng Xu, Z.-Y. Cheng, Dana Olson, T. Mai, Q. M. Zhang, G. Kavarnos, Ferroelectric and electromechanical properties of poly(vinylidene-fluoride–trifluoroethylene–chlorotrifluoroethylene) terpolymer Applied Physics Letters. ,vol. 78, pp. 2360- 2362 ,(2001) , 10.1063/1.1358847
C. M. Roland, J. T. Garrett, R. Casalini, D. F. Roland, P. G. Santangelo, S. B. Qadri, Mechanical and Electromechanical Properties of Vinylidene Fluoride Terpolymers Chemistry of Materials. ,vol. 16, pp. 857- 861 ,(2004) , 10.1021/CM034822H
Z-Y Cheng, T-B Xu, Vivek Bharti, Shexi Wang, QM Zhang, None, Transverse strain responses in the electrostrictive poly(vinylidene fluoride–trifluorethylene) copolymer Applied Physics Letters. ,vol. 74, pp. 1901- 1903 ,(1999) , 10.1063/1.123707
F. Xia, Z.-Y. Cheng, H.S. Xu, H.F. Li, Q.M. Zhang, G.J. Kavarnos, R.Y. Ting, G. Abdul-Sadek, K.D. Belfield, High electromechanical responses in a poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) terpolymer Advanced Materials. ,vol. 14, pp. 1574- 1577 ,(2002) , 10.1002/1521-4095(20021104)14:21<1574::AID-ADMA1574>3.0.CO;2-#
Z.-Y. Cheng, Dana Olson, Haisheng Xu, Feng Xia, J. S. Hundal, Q. M. Zhang, Fred B. Bateman, G. J. Kavarnos, T. Ramotowski, Structural Changes and Transitional Behavior Studied from Both Micro- and Macroscale in the High-Energy Electron-Irradiated Poly(vinylidene fluoride−trifluoroethylene) Copolymer Macromolecules. ,vol. 35, pp. 664- 672 ,(2002) , 10.1021/MA0112265