Steam Reforming of Biogas on Nickel Fiber Mat Catalysts

作者: Quynh Thi Phuong Bui , Yong-Min Kim , Chang-Won Yoon , Suk-Woo Nam , None

DOI: 10.5855/ENERGY.2011.20.3.252

关键词:

摘要: Nickel fiber mat was investigated as a potential structured catalyst for steam reforming of biogas in the temperature range 600-700℃. The activity as-received very low owing to smooth surface fibers. Pretreatment by oxidation followed reduction under methane partial condition significantly improved catalytic activity, although degradation found during reaction due and sintering. This deactivation retarded supplying additional hydrogen inlet gases or coating CeO₂ over surfaces.

参考文章(13)
Ottmar Knacke, Ihsan Barin, Thermochemical properties of inorganic substances ,(1973)
Q.G. Yan, W.Z. Weng, H.L. Wan, H. Toghiani, R.K. Toghiani, C.U. Pittman, Activation of methane to syngas over a Ni/TiO2 catalyst Applied Catalysis A-general. ,vol. 239, pp. 43- 58 ,(2003) , 10.1016/S0926-860X(02)00351-4
D KING, J STROHM, X WANG, H ROH, C WANG, Y CHIN, Y WANG, Y LIN, R ROZMIAREK, P SINGH, Effect of nickel microstructure on methane steam-reforming activity of Ni–YSZ cermet anode catalyst Journal of Catalysis. ,vol. 258, pp. 356- 365 ,(2008) , 10.1016/J.JCAT.2008.06.031
Kee Young Koo, Hyun-Seog Roh, Un Ho Jung, Wang Lai Yoon, CeO2 Promoted Ni/Al2O3 Catalyst in Combined Steam and Carbon Dioxide Reforming of Methane for Gas to Liquid (GTL) Process Catalysis Letters. ,vol. 130, pp. 217- 221 ,(2009) , 10.1007/S10562-009-9867-4
Andrew P. Grosvenor, Mark C. Biesinger, Roger St.C. Smart, N. Stewart McIntyre, New interpretations of XPS spectra of nickel metal and oxides Surface Science. ,vol. 600, pp. 1771- 1779 ,(2006) , 10.1016/J.SUSC.2006.01.041
Prashant Kumar, Yanping Sun, Raphael O. Idem, Nickel-Based Ceria, Zirconia, and Ceria–Zirconia Catalytic Systems for Low-Temperature Carbon Dioxide Reforming of Methane Energy & Fuels. ,vol. 21, pp. 3113- 3123 ,(2007) , 10.1021/EF7002409
Shi Hong Zhang, Ming Xi Li, Jae Hong Yoon, Tong Yul Cho, Yi Zhu He, Chan Gyu Lee, Microstructure and corrosion resistance of Ni-based alloy laser coatings with nanosize CeO2 addition Science and Technology of Advanced Materials. ,vol. 9, pp. 035002- ,(2008) , 10.1088/1468-6996/9/3/035002
Sung Ho Kim, Suk-Woo Nam, Tae-Hoon Lim, Ho-In Lee, Effect of pretreatment on the activity of Ni catalyst for CO removal reaction by water–gas shift and methanation Applied Catalysis B-environmental. ,vol. 81, pp. 97- 104 ,(2008) , 10.1016/J.APCATB.2007.12.009
Arun SK Raju, Chan S Park, Joseph M Norbeck, None, Synthesis gas production using steam hydrogasification and steam reforming Fuel Processing Technology. ,vol. 90, pp. 330- 336 ,(2009) , 10.1016/J.FUPROC.2008.09.011