Formation of β-C3N4 grains by nitrogen-ion-beam-assisted deposition

作者: X.W. Su , H.W. Song , F.Z. Cui , W.Z. Li , H.D. Li

DOI: 10.1016/S0257-8972(95)02809-9

关键词:

摘要: Abstract Carbon nitride thin films were prepared by nitrogen-ion-beam-assisted deposition. Auger electron spectroscopy shows that the N/C atomic composition ratio increases with increasing current density and decreasing bombarding energy of nitrogen ion beam. At a 200 eV 0.2 mA cm −2 , maximum 0.54 is obtained crystalline β -C 3 N 4 grains dimensions about 0.1 μm are observed transmission microscopy. This film displays high Knoop hardness 4450 kgf mm resistivity 10 9 Ω cm.

参考文章(15)
Cui Fuzhai, A M Vredenberg, R de Reus, F W Saris, Formation of Nitride Cu 3 N by MeV N-Ion Implantation into Cu Chinese Physics Letters. ,vol. 8, pp. 525- 528 ,(1991) , 10.1088/0256-307X/8/10/009
H W Song, F Z Cui, X M He, W Z Li, H D Li, Carbon nitride films synthesized by NH3-ion-beam-assisted deposition Journal of Physics: Condensed Matter. ,vol. 6, pp. 6125- 6129 ,(1994) , 10.1088/0953-8984/6/31/011
Kin Man Yu, Marvin L. Cohen, E. E. Haller, W. L. Hansen, Amy Y. Liu, I. C. Wu, Observation of crystalline C3N4. Physical Review B. ,vol. 49, pp. 5034- 5037 ,(1994) , 10.1103/PHYSREVB.49.5034
D. Marton, K. J. Boyd, A. H. Al-Bayati, S. S. Todorov, J. W. Rabalais, Carbon nitride deposited using energetic species: A two-phase system. Physical Review Letters. ,vol. 73, pp. 118- 121 ,(1994) , 10.1103/PHYSREVLETT.73.118
Kiyoshi Ogata, José Fernando Diniz Chubaci, Fuminori Fujimoto, Properties of carbon nitride films with composition ratio C/N=0.5–3.0 prepared by the ion and vapor deposition method Journal of Applied Physics. ,vol. 76, pp. 3791- 3796 ,(1994) , 10.1063/1.358497
C. Niu, Y. Z. Lu, C. M. Lieber, Experimental Realization of the Covalent Solid Carbon Nitride Science. ,vol. 261, pp. 334- 337 ,(1993) , 10.1126/SCIENCE.261.5119.334
M. Ghanashyam Krishna, K.R. Gunasekhar, S. Mohan, Low temperature synthesis of thin films of carbon nitride Journal of Materials Research. ,vol. 10, pp. 1083- 1085 ,(1995) , 10.1557/JMR.1995.1083
François Rossi, Bernard Andre, A. van Veen, P.E. Mijnarends, H. Schut, F. Labohm, Marie Paule Delplancke, Hugh Dunlop, Eric Anger, Physical properties of nitrogenated amorphous carbon films produced by ion-beam-assisted deposition Thin Solid Films. ,vol. 253, pp. 85- 89 ,(1994) , 10.1016/0040-6090(94)90299-2
Amy Y. Liu, Renata M. Wentzcovitch, Stability of carbon nitride solids Physical Review B. ,vol. 50, pp. 10362- 10365 ,(1994) , 10.1103/PHYSREVB.50.10362
J.P. Rivière, D. Texier, J. Delafond, M. Jaouen, E.L. Mathé, J. Chaumont, Formation of the crystalline β-C3N4 phase by dual ion beam sputtering deposition Materials Letters. ,vol. 22, pp. 115- 118 ,(1995) , 10.1016/0167-577X(94)00233-9