Large scale synthesis of carbon nanofibers by catalytic decomposition of ethane on nickel nanoclusters decorating carbon nanotubes

作者: Cuong Pham-Huu , Nicolas Keller , Vladimir V. Roddatis , Gerhard Mestl , Robert Schlögl

DOI: 10.1039/B106512M

关键词:

摘要: A large scale synthesis of carbon nanofibers with a controlled diameter about 50 nm has been achieved at relatively low temperatures (550–650 °C) by the decomposition ethane on nanotube supported nickel catalyst. The can be used as catalyst or support without subsequent purification, due to use nanotubes support, high nanofiber yields, and purity obtained.

参考文章(21)
V. P. Dravid, X. Lin, Y. Wang, X. K. Wang, A. Yee, J. B. Ketterson, R. P. H. Chang, Buckytubes and Derivatives: Their Growth and Implications for Buckyball Formation Science. ,vol. 259, pp. 1601- 1604 ,(1993) , 10.1126/SCIENCE.259.5101.1601
Nelly M. Rodriguez, Alan Chambers, R. Terry K. Baker, Catalytic Engineering of Carbon Nanostructures Langmuir. ,vol. 11, pp. 3862- 3866 ,(1995) , 10.1021/LA00010A042
Alan M. Cassell, Jeffrey A. Raymakers, Jing Kong, Hongjie Dai, Large Scale CVD Synthesis of Single-Walled Carbon Nanotubes Journal of Physical Chemistry B. ,vol. 103, pp. 6484- 6492 ,(1999) , 10.1021/JP990957S
D. S. Bethune, C. H. Kiang, M. S. de Vries, G. Gorman, R. Savoy, J. Vazquez, R. Beyers, Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls Nature. ,vol. 363, pp. 605- 607 ,(1993) , 10.1038/363605A0
Lijie Ci, Yanhui Li, Bingqing Wei, Ji Liang, Cailu Xu, Dehai Wu, Preparation of carbon nanofibers by the floating catalyst method Carbon. ,vol. 38, pp. 1933- 1937 ,(2000) , 10.1016/S0008-6223(00)00030-0
Nicolas Keller, Cuong Pham-Huu, Marc J Ledoux, Claude Estournes, Gabrielle Ehret, Preparation and characterization of SiC microtubes Applied Catalysis A-general. ,vol. 187, pp. 255- 268 ,(1999) , 10.1016/S0926-860X(99)00223-9
K. Hernadi, A. Fonseca, J.B. Nagy, D. Bernaerts, A.A. Lucas, Fe-catalyzed carbon nanotube formation Carbon. ,vol. 34, pp. 1249- 1257 ,(1996) , 10.1016/0008-6223(96)00074-7
F Salman, C Park, R.T.K Baker, Hydrogenation of crotonaldehyde over graphite nanofiber supported nickel Catalysis Today. ,vol. 53, pp. 385- 394 ,(1999) , 10.1016/S0920-5861(99)00132-7
Sumio Iijima, Helical microtubules of graphitic carbon Nature. ,vol. 354, pp. 56- 58 ,(1991) , 10.1038/354056A0
Satoshi Sato, Ryoji Takahashi, Toshiaki Sodesawa, Fumio Nozaki, Xing-Zhou Jin, Satoshi Suzuki, Tomohiro Nakayama, Mass-Transfer Limitation in Mesopores of Ni–MgO Catalyst in Liquid-Phase Hydrogenation Journal of Catalysis. ,vol. 191, pp. 261- 270 ,(2000) , 10.1006/JCAT.1999.2797