Modification of industrial BOF slag: Formation of MgFe2O4 and recycling of iron

作者: Peng Xue , Dongfeng He , Anjun Xu , Zongxi Gu , Qixing Yang

DOI: 10.1016/J.JALLCOM.2017.04.142

关键词:

摘要: Abstract Efficient recycling of iron oxide from industrial BOF (basic oxygen furnace) slags has always been an issue in metallurgy. In this study, a new method was developed for the efficient oxide: It transformed into magnesioferrite spinel (MgFe2O4) by mixing slag with 6.00% SiO2 first, and then modified got cooled down 1400 °C to 1270 °C at rate 1 °C/min. Finally, Fe resources were recycled magnetic separation. Various experiments analyses such as XRD, SEM–EDS analyses, Factsage thermodynamic simulation, magnetization characterization, dry separation, chemical analysis carried out. The results show that obtained MgFe2O4 high melting point (1716.76 °C theory) ferromagnetism (specific susceptibility (8.03–206.84) × 10−5 m3/kg). Therefore, it could be separated weakly (0.024–0.136) × 10−5 m3/kg). Furthermore, applied different slags. yield increased above 80% when content Fe2O3 range 25.81–46.90%. After modification total 15.80%, 21.20% 37.00% slag. This is better than direct separation without any treatment. reused either sintering or splashing material. nonmagnetic can used produce value-added building materials. Hence, recycle slags, achieving sustainable development steel industry.

参考文章(22)
Nobuo Sano, Norio Oka, Muxing Guo, Kazuki Morita, Resurrection of the iron and phosphorus resource in steel-making slag Journal of Material Cycles and Waste Management. ,vol. 4, pp. 93- 101 ,(2002) , 10.1007/S10163-001-0067-6
J Pesl, R.H Eric, High temperature carbothermic reduction of Fe2O3-TiO2-MxOy oxide mixtures Minerals Engineering. ,vol. 15, pp. 971- 984 ,(2002) , 10.1016/S0892-6875(02)00136-X
Zukhra C. Kadirova, Mirabbos Hojamberdiev, Longli Bo, Rustam Hojiyev, Kiyoshi Okada, Simultaneous removal of NH4+, H2PO4− and Ni2+ from aqueous solution by thermally activated combinations of steel converter slag and spent alumina catalyst Journal of water process engineering. ,vol. 8, pp. 151- 159 ,(2015) , 10.1016/J.JWPE.2015.10.004
Jin-tao Gao, Shi-qi Li, Yan-ting Zhang, Yan-ling Zhang, Pei-yu Chen, Ping Shen, Process of Re-Resourcing of Converter Slag Journal of Iron and Steel Research International. ,vol. 18, pp. 32- 39 ,(2011) , 10.1016/S1006-706X(12)60006-5
Jan Berggren, Olav Foss, Ingvald Roti, Hideyuki Okinaka, Koji Kosuge, Sukeji Kachi, Refinement of the Crystal Structure of Dicalcium Ferrite, Ca2Fe2O5. Acta Chemica Scandinavica. ,vol. 25, pp. 3616- 3624 ,(1971) , 10.3891/ACTA.CHEM.SCAND.25-3616
E.-E. Chang, An-Chia Chiu, Shu-Yuan Pan, Yi-Hung Chen, Chung-Sung Tan, Pen-Chi Chiang, Carbonation of basic oxygen furnace slag with metalworking wastewater in a slurry reactor International Journal of Greenhouse Gas Control. ,vol. 12, pp. 382- 389 ,(2013) , 10.1016/J.IJGGC.2012.11.026
Jesse Stimson, Gi-Tak Chae, Carol J. Ptacek, Monica B. Emelko, Maria M. Mesquita, Ricardo A. Hirata, David W. Blowes, Basic oxygen furnace slag as a treatment material for pathogens: Contribution of inactivation and attachment in virus attenuation Water Research. ,vol. 44, pp. 1150- 1157 ,(2010) , 10.1016/J.WATRES.2009.11.054
Wenbin Dai, Yu Li, Daqiang Cang, Zhaobo Liu, Yong Fan, BOF Slag Glass-ceramics Prepared in Different Atmospheres from Parents Glasses with Various Reduction Degree Isij International. ,vol. 54, pp. 2672- 2677 ,(2014) , 10.2355/ISIJINTERNATIONAL.54.2672