Effects of Electrode–Molecule Binding and Junction Geometry on the Single-Molecule Conductance of bis-2,2′:6′,2″-Terpyridine-based Complexes
作者： Ross Davidson , Oday A. Al-Owaedi , David C. Milan , Qiang Zeng , Joanne Tory
DOI: 10.1021/ACS.INORGCHEM.5B02094
关键词:
摘要: The single molecule conductances of a series bis-2,2′:6′,2″-terpyridine complexes featuring Ru(II), Fe(II), and Co(II) metal ions trimethylsilylethynyl (Me3SiC≡C−) or thiomethyl (MeS-) surface contact groups have been determined. In the absence electrochemical gating, these behave as tunneling barriers, with conductance properties determined more by strength electrode–molecule structure “linker” than nature metal-ion redox complex.
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