Hard, tough and strong ZrO2–WC composites from nanosized powders

作者: Guy Anné , Stijn Put , Kim Vanmeensel , Dongtao Jiang , Jef Vleugels

DOI: 10.1016/J.JEURCERAMSOC.2004.01.015

关键词:

摘要: Yttria-stabilised zirconia (Y-TZP) based composites with a tungsten carbide (WC) content up to 50 vol.% were prepared from nanopowders by means of conventional hot pressing. The mechanical properties investigated as function the WC content. hardness increased 12.3 GPa for pure Y-TZP 16.4 composite WC, whereas bending strength reached maximum 1551 MPa 20 composite. toughness could be optimised judicious adjustment overall yttria mixing monoclinic and 3 mol% Y2O3 co-precipitated ZrO2 starting powders. An optimum fracture 9 m 1/2 was obtained 40% an 2 mol%. hardness, well ultrafine grained nanosized source significantly higher than micron-sized WC. experimentally measured contribution different observed toughening mechanisms evaluated Transformation found major mechanism in ZrO2–WC 30 crack deflection bridging is significant at secondary phase above vol.%. © 2004 Elsevier Ltd. All rights reserved.

参考文章(22)
R. Telle, G. Petzow, Strengthening and toughening of boride and carbide hard material composites Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. pp. 97- 104 ,(1988) , 10.1016/0025-5416(88)90485-5
Richard H. J. Hannink, Patrick M. Kelly, Barry C. Muddle, Transformation Toughening in Zirconia‐Containing Ceramics Journal of the American Ceramic Society. ,vol. 83, pp. 461- 487 ,(2004) , 10.1111/J.1151-2916.2000.TB01221.X
Zbigniew Pędzich, Krzysztof Haberko, Jan Piekarczyk, Marek Faryna, Lidia Lityńska, Zirconia matrix-tungsten carbide particulate composites manufactured by hot-pressing technique Materials Letters. ,vol. 36, pp. 70- 75 ,(1998) , 10.1016/S0167-577X(98)00010-X
Zbigniew Pędzich, Krzysztof Haberko, Toughening Mechanisms in the TZP - WC Particulate Composites Key Engineering Materials. pp. 2076- 2079 ,(1997) , 10.4028/WWW.SCIENTIFIC.NET/KEM.132-136.2076
R. Telle, S. Meyer, G. Petzow, E.D. Franz, Sintering behaviour and phase reactions of TiB2 with ZrO2 additives Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. pp. 125- 129 ,(1988) , 10.1016/0025-5416(88)90488-0
S. Stemmer, J. Vleugels, O. Van Der Biest, Transmission Electron Microscopy (TEM) Studies of Interfaces in TiB 2 -ZrO 2 Composites MRS Proceedings. ,vol. 458, pp. 133- ,(1996) , 10.1557/PROC-458-133
Hideo Toraya, Masahiro Yoshimura, Shigeyuki Somiya, Calibration Curve for Quantitative Analysis of the Monoclinic‐Tetragonal ZrO2 System by X‐Ray Diffraction Journal of the American Ceramic Society. ,vol. 67, ,(1984) , 10.1111/J.1151-2916.1984.TB19715.X
B. Basu, Jef Vleugels, Omer Van der Biest, Toughness Optimisation of ZrO2-TiB2 Composites Key Engineering Materials. pp. 1177- 1180 ,(2001) , 10.4028/WWW.SCIENTIFIC.NET/KEM.206-213.1177
P. CHANTIKUL, G. R. ANSTIS, B. R. LAWN, D. B. MARSHALL, A Critical Evaluation of Indentation Techniques for Measuring Fracture Toughness: II, Strength Method Journal of the American Ceramic Society. ,vol. 64, pp. 539- 543 ,(1981) , 10.1111/J.1151-2916.1981.TB10321.X
Jef Vleugels, Omer Biest, Development and Characterization of Y2O3‐Stabilized ZrO2 (Y‐TZP) Composites with TiB2, TiN, TiC, and TiC0.5N0.5 Journal of the American Ceramic Society. ,vol. 82, pp. 2717- 2720 ,(2004) , 10.1111/J.1151-2916.1999.TB02147.X