Binary ionogenic equilibria

摘要: Abstract A general treatment of binary solution equilibria, in which two molecules the same species (A+A) or different (A+B) form ions, is developed and intervention ion pairs considered; no such to be found literature. Equations are derived procedures outlined, whereby all equilibrium constants ionic conductivity electrolyte can determined. When [B]>>[A], relevant equation becomes that for well-known Ostwald ionisation equilibrium. The equations applied real systems inlude self-ionising metal halides new self-ionisation discussed. In last Section it shown how activity coefficients introduced into equilibria.