Studies of Interfacial Interaction between Polyaniline and Corn Gluten Meal and their Effect on Electroactive and Free Radical Scavenging Properties

作者: Walt V. K. Wheelwright , Sudip Ray , Ralph P. Cooney

DOI: 10.1080/15421406.2015.1043212

关键词:

摘要: Preparation and characterisation of Corn Gluten Meal (CGM)-polyaniline (PANI) blends by direct deposition PANI onto the CGM surface via in situ oxidative polymerisation aniline was studied. A series different CGM-PANI were prepared varying CGM-aniline feed mass ratios 95:5, 90:10, 80:20, 70:30, 60:40 50:50. The blend compositions studied Elemental analysis. Interfacial interactions between nitrogen containing groups from detected X-ray photoelectron spectroscopy FTIR spectroscopy. Formation electrically conductive emeraldine salt form these evident their characteristic dark green colour. conductivity increased with increasing content range 10−2 S·cm−1 to 2 S·cm−1. Similarly all showed free radical scavenging activity effect more pronounced at higher content. Therefore inclusion introduced valuable functional properties wh...

参考文章(37)
P Argos, K Pedersen, M D Marks, B A Larkins, A structural model for maize zein proteins. Journal of Biological Chemistry. ,vol. 257, pp. 9984- 9990 ,(1982) , 10.1016/S0021-9258(18)33974-7
Walt V. K. Wheelwright, Allan J. Easteal, Sudip Ray, Michél K. Nieuwoudt, A one-step approach for esterification of zein with methanol Journal of Applied Polymer Science. ,vol. 127, pp. 3500- 3505 ,(2013) , 10.1002/APP.37631
D. J. Sessa, K. K. Woods, Purity Assessment of Commercial Zein Products After Purification Journal of the American Oil Chemists' Society. ,vol. 88, pp. 1037- 1043 ,(2011) , 10.1007/S11746-011-1765-4
Zun-li Mo, Zhong-li Zhao, Hong Chen, Gui-ping Niu, Hua-feng Shi, Heterogeneous preparation of cellulose–polyaniline conductive composites with cellulose activated by acids and its electrical properties Carbohydrate Polymers. ,vol. 75, pp. 660- 664 ,(2009) , 10.1016/J.CARBPOL.2008.09.010
Qiangxian Wu, Hiroshi Sakabe, Seiichiro Isobe, Processing and Properties of Low Cost Corn Gluten Meal/Wood Fiber Composite Industrial & Engineering Chemistry Research. ,vol. 42, pp. 6765- 6773 ,(2003) , 10.1021/IE0303045
Yingfeng Zuo, Jiyou Gu, Long Yang, Zhibang Qiao, Haiyan Tan, Yanhua Zhang, Synthesis and characterization of maleic anhydride esterified corn starch by the dry method. International Journal of Biological Macromolecules. ,vol. 62, pp. 241- 247 ,(2013) , 10.1016/J.IJBIOMAC.2013.08.032
Ashveen V. Nand, Sudip Ray, Allan J. Easteal, Geoffrey I.N. Waterhouse, Marija Gizdavic-Nikolaidis, Ralph P. Cooney, Jadranka Travas-Sejdic, Paul A. Kilmartin, Factors affecting the radical scavenging activity of polyaniline Synthetic Metals. ,vol. 161, pp. 1232- 1237 ,(2011) , 10.1016/J.SYNTHMET.2011.04.010
Wojciech Dzwolak, Minoru Kato, Yoshihiro Taniguchi, Fourier transform infrared spectroscopy in high-pressure studies on proteins. Biochimica et Biophysica Acta. ,vol. 1595, pp. 131- 144 ,(2002) , 10.1016/S0167-4838(01)00340-5
M.D.H. Beg, K.L. Pickering, S.J. Weal, Corn gluten meal as a biodegradable matrix material in wood fibre reinforced composites Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 412, pp. 7- 11 ,(2005) , 10.1016/J.MSEA.2005.08.015