Quantum Limits of the Electrostatic Image Force Theory

作者: R. G. Sachs , D. L. Dexter

DOI: 10.1063/1.1699595

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摘要: The quantum mechanical problem of the interaction a charged macroscopic body with metal surface is treated by means variation method. resulting expression for energy same as that obtained classical image force method except three correction terms. These corrections are caused change in kinetic associated concentration electrons on metal, reduction electron‐electron from anti‐symmetrization wave function and effect finite thickness charge. It found these terms negligible distances between such structure effects important.

参考文章(3)
J. Bardeen, The Image and Van der Waals Forces at a Metallic Surface Physical Review. ,vol. 58, pp. 727- 736 ,(1940) , 10.1103/PHYSREV.58.727
J. E. Lennard-Jones, Processes of adsorption and diffusion on solid surfaces Transactions of The Faraday Society. ,vol. 28, pp. 333- 359 ,(1932) , 10.1039/TF9322800333