Hydrogen storage in thin film metal hydrides

作者: H. Wenzl , K.-H. Klatt , P. Meuffels , K. Papathanassopoulos

DOI: 10.1016/0022-5088(83)90360-0

关键词:

摘要: Sandwich films were prepared by vapour deposition on quartz crystals or polycrystalline aluminium foil, e.g. quartz/V(1 μm)/Pd(100 nm) and Al(20 /V(10 nm). The vanadium can be hydrided almost reversibly from the gas phase within seconds to VH0.5 at 300 K a hydrogen pressure of 1 bar min VH1.8 30 bar. known diagrams V-H2 system reproduced. Al/Pd/V/Pd used in prototype storage containers: 2% mass fraction was stored, similar TiFe hydride storage, but much higher heat exchange rate attained.

参考文章(4)
W. Pesch, T. Schober, H. Wenzl, A TEM study of the phase diagrams VH and VD Scripta Metallurgica. ,vol. 16, pp. 307- 312 ,(1982) , 10.1016/0036-9748(82)90358-1
K Papathanassopoulos, H Wenzl, Pressure-composition isotherms of hydrogen and deuterium in vanadium films measured with a vibrating quartz microbalance Journal of Physics F: Metal Physics. ,vol. 12, pp. 1369- 1381 ,(1982) , 10.1088/0305-4608/12/7/009
R. V. Bucur, T. B. Flanagan, The Effect of the Absorption of Hydrogen and Deuterium on the Frequency of a Quartz-Palladium Resonator Zeitschrift für Physikalische Chemie. ,vol. 88, pp. 225- 241 ,(1974) , 10.1524/ZPCH.1974.88.5_6.225