Reversible Chlorine Electrode for the Measurement of Electromotive Force in Molten Salt Cells
作者： Seymour Senderoff , G. W. Mellors
DOI: 10.1063/1.1716125
关键词:
摘要: A reversible chlorine electrode which may be used in molten salts up to temperatures of at least 900°C is described. Chlorine gas forced through a porous graphite cylinder contact with the solution under study. The was tested Ag|AgCl|Cl2 (graphite) cell and an exactly linear dependence emf on temperature found for range 530 920°C. Excellent agreement earlier measurements below 600°C results indicate that calculated values based thermal data high are high. Emf from 920°C given.
scitation.org
aip.org
sci-hub.se 参考文章(5)
Seymour Senderoff, Abner Brenner, The Electrolytic Preparation of Molybdenum from Fused Salts Journal of The Electrochemical Society. ,vol. 101, pp. 31- 38 ,(1954) , 10.1149/1.2781202
Paul Drossbach, Discussion of “Theoretical Electromotive Forces for Cells Containing A Single Solid or Molten Chloride Electrolyte” [Walter J. Hamer, Marjorie S. Malmberg, and Bernard Rubin (pp. 8–16, Vol. 103)] Journal of The Electrochemical Society. ,vol. 103, pp. 700- 701 ,(1956) , 10.1149/1.2430200
Walter J. Hamer, Marjorie S. Malmberg, Bernard Rubin, THEORETICAL ELECTROMOTIVE FORCES FOR CELLS CONTAINING A SINGLE SOLID OR MOLTEN CHLORIDE ELECTROLYTE Journal of The Electrochemical Society. ,vol. 103, pp. 8- 16 ,(1956) , 10.1149/1.2430236
Edward J. Salstrom, The Free Energy of Reactions Involving the Fused Chlorides and Bromides of Lead, Zinc and Silver Journal of the American Chemical Society. ,vol. 55, pp. 2426- 2428 ,(1933) , 10.1021/JA01333A031
Kurt H. Stern, Electrode Potentials in Fused Systems. II. A Study of the AgCl-KCl System. The Journal of Physical Chemistry. ,vol. 60, pp. 679- 681 ,(1956) , 10.1021/J150539A043