A new lead Mo(IV) phosphate with a tunnel structure: Pb2Mo2O(PO4)2P2O7
作者： A. Leclaire , J. Chardon , B. Raveau
DOI: 10.1016/S0022-4596(03)00018-5
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摘要: Abstract A molybdenum (IV) phosphate containing lead, Pb 2 Mo (PO 4 )2P O 7 , has been synthesized for the first time. It crystallizes in space group C 2/ c with a =14.098(1) A, b =14.187(2) A, =6.5592(4) A and β =102.08(1)°. Its original tunnel structure, built up of 11 bioctahedra, P PO groups can be described from assemblage [Mo 24 ] ∞ ribbons interconnected through monophosphate groups. The stereoactivity 6 s lone pair 2+ which is surrounded by nine oxygen atoms, discussed.
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A. Leclaire, J. Chardon, J. Provost, B. Raveau, A lead molybdenum(V) monophosphate with a tunnel structure: Pb3(MoO)3(PO4)5 Journal of Solid State Chemistry. ,vol. 163, pp. 308- 312 ,(2002) , 10.1006/JSSC.2001.9416
K.H. Lii, J.J. Chen, S.L. Wang, NaMo2P3O12: A new phosphate of Mo(IV) Journal of Solid State Chemistry. ,vol. 78, pp. 93- 97 ,(1989) , 10.1016/0022-4596(89)90131-X
A. Leclaire, B. Raveau, Small atomic displacements in the molybdenophosophates AMo2P3O12 (A = K,Rb,Ti) Acta Crystallographica Section C-crystal Structure Communications. ,vol. 44, pp. 226- 229 ,(1988) , 10.1107/S0108270187006516
A. Leclaire, M.M. Barel, J. Chardon, B. Raveau, A Mo(IV) Monophosphate, BaMo(PO4)2, with the Yavapaiite Layer Structure Journal of Solid State Chemistry. ,vol. 116, pp. 364- 368 ,(1995) , 10.1006/JSSC.1995.1227
L. Lezama, J.M. Rojo, J.L. Mesa, T. Rojo, R. Olazcuaga, Synthesis and magnetic and electrical properties of the molybdenum and tungsten pyrophosphates MP2O7 (M=Mo, W) Journal of Solid State Chemistry. ,vol. 115, pp. 146- 151 ,(1995) , 10.1006/JSSC.1995.1113
Fernando Zocchi, Some considerations about equations correlating valence and length of a chemical bond Solid State Sciences. ,vol. 3, pp. 383- 386 ,(2001) , 10.1016/S1293-2558(00)01142-0
A. Leclaire, J.C. Monier, B. Raveau, TIMoIV2P3O12: A molybdenophosphate with a tunnel structure Journal of Solid State Chemistry. ,vol. 59, pp. 301- 305 ,(1985) , 10.1016/0022-4596(85)90297-X
M. M. Borel, A. Leclaire, A. Grandin, B. Raveau, Structure of molybdenum (IV) diphosphate MoP2O7 European Journal of Solid State and Inorganic Chemistry. ,vol. 25, pp. 323- 328 ,(1988)
A. Leclaire, J. Chardon, S. Boudin, J. Provost, B. Raveau, A lead phosphomolybdenum purple bronze: Pb0.9PMo5O17 Chemistry of Materials. ,vol. 14, pp. 3427- 3431 ,(2002) , 10.1021/CM020217N