Aromatics from pyrones: para-substituted alkyl benzoates from alkenes, coumalic acid and methyl coumalate

作者: George A. Kraus , Sean Riley , Travis Cordes

DOI: 10.1039/C1GC15650K

关键词:

摘要: The Diels–Alder reaction of coumalic acid and methyl coumalate with unactivated alkenes provides only para-substituted adducts in good yield.

参考文章(7)
Kamyar Afarinkia, Victoria Vinader, Todd D. Nelson, Gary H. Posner, Diels-Alder cycloadditions of 2-pyrones and 2-pyridones Tetrahedron. ,vol. 48, pp. 9111- 9171 ,(1992) , 10.1016/S0040-4020(01)85607-6
Muriel Amatore, Corinne Gosmini, Synthesis of functionalised diarylmethanes via a cobalt-catalysed cross-coupling of arylzinc species with benzyl chlorides. Chemical Communications. ,vol. 40, pp. 5019- 5021 ,(2008) , 10.1039/B809626K
I. W. Ashworth, M. C. Bowden, B. Dembofsky, D. Levin, W. Moss, E. Robinson, N. Szczur, J. Virica, A New Route for Manufacture of 3-Cyano-1-naphthalenecarboxylic Acid Organic Process Research & Development. ,vol. 7, pp. 74- 81 ,(2003) , 10.1021/OP025571L
Patrick M. Delaney, Duncan L. Browne, Harry Adams, Andrew Plant, Joseph P.A. Harrity, A 2-pyrone cycloaddition route to functionalised aromatic boronic esters Tetrahedron. ,vol. 64, pp. 866- 873 ,(2008) , 10.1016/J.TET.2007.08.118
Yoh-ichi Matsushita, Kei Sakamoto, Taro Murakami, Takanao Matsui, A Convenient Synthesis of Methyl 4-Substituted Benzoates via Diels-Alder Reaction in the Presence of Palladium on Activated Carbon Synthetic Communications. ,vol. 24, pp. 3307- 3313 ,(1994) , 10.1080/00397919408010254
George A. Kraus, Synthetic Methods for the Preparation of 1,3‐Propanediol Clean-soil Air Water. ,vol. 36, pp. 648- 651 ,(2008) , 10.1002/CLEN.200800084
T. A. Bryson, D. M. Donelson, Diels-Alder synthesis of hindered aromatic amines The Journal of Organic Chemistry. ,vol. 42, pp. 2930- 2931 ,(1977) , 10.1021/JO00437A033