α-Functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations

作者: Irina Jovel , Saisuree Prateeptongkum , Ralf Jackstell , Nadine Vogl , Christoph Weckbecker

DOI: 10.1039/B924674F

关键词:

摘要: Novel catalytic α-functionalizations of non-activated aliphatic amines with silylated alkynes are reported. In the presence Shvo catalyst alkylations and alkynylations proceed highly selectively to branched amines.

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