MODIFIED CELLULOSE FINE FIBERS AND METHOD FOR PRODUCING SAME

作者: Lin Lianzhen , Maruta Ayako

DOI:

关键词:

摘要: Modified fine cellulose fibers are produced by impregnating a with reactive fibrillation solution or mixture containing catalyst including base an organic acid catalyst, monobasic carboxylic anhydride, and aprotic solvent having donor number of not less than 26 to esterify chemically fibrillate the cellulose. This method provides simple efficient process for producing modified that have diameter from several nano-meters submicrometers, large aspect ratio, high degree crystallinity, damage in shape crystalline structure fibers, excellent dispersibility solvent; The may contain pyridine compound. anhydride be C 2-4 aliphatic monocarboxylic anhydride. resulting crystallinity 70%, average fiber 20 800 nm, length 1 200 µm.

参考文章(17)
Daisuke Kabusaki, Fumiaki Nakatsubo, Kazuhiro Shintani, Hiromasa Kataoka, Akihiro Sato, Hiroyuki Yano, Tomoaki Yoshimura, Hiroaki Okumura, Yuko Igarashi, Takeshi Semba, Kazuo Kitagawa, Method for producing resin composition comprising modified microfibrillated plant fibers, and same resin composition ,(2013)
Gamini Samaranayake, Wolfgang G. Glasser, Cellulose derivatives with low DS. I. A novel acylation system Carbohydrate Polymers. ,vol. 22, pp. 1- 7 ,(1993) , 10.1016/0144-8617(93)90159-2
Romeu Casarano, Haq Nawaz, Shirley Possidonio, Valdinéia C. da Silva, Omar A. El Seoud, A convenient solvent system for cellulose dissolution and derivatization: Mechanistic aspects of the acylation of the biopolymer in tetraallylammonium fluoride/dimethyl sulfoxide Carbohydrate Polymers. ,vol. 86, pp. 1395- 1402 ,(2011) , 10.1016/J.CARBPOL.2011.06.051
Masatoshi Iji, Kiyohiko Toyama, Shukichi Tanaka, Method for producing cellulose derivative and cellulose derivative ,(2014)
Shin-ichi Ishiguro, Morito Komiya, Nonaqueous Solution Coordination Chemistry Studied by Titration Calorimetry Netsu Sokutei. ,vol. 28, pp. 135- 143 ,(2001) , 10.11311/JSCTA1974.28.135
晴幸 米田, Haruyuki Yoneda, 勝成 安田, Masanari Yasuda, Cellulose ester excellent in solvent resistance and its production ,(1993)
Aruberuto Barudeinii, Roberuto Reonii, Jiyanfuranko Anjierinii, ACETYL DERIVATIVE OF CELLULOSE AND ITS MANUFACTURE ,(1981)