The synthesis and reactivity of some indenyl and bis-indenyl ruthenium carbonyl complexes
作者： Venugopal Shanmugham Sridevi , Weng Kee Leong
DOI: 10.1016/J.JORGANCHEM.2007.07.023
关键词:
摘要: Abstract The reaction of [Ru3(CO)12] (1), with indene in refluxing xylene affords [{(η5-C9H7)Ru(CO)2}2] (2), high yield. An analogous 1 2-phenylindene the expected dinuclear complex [{(η5-C9H6Ph)Ru(CO)2}2] (5), and a heptaruthenium cluster [(C9H4Ph)Ru7(μ-H)(μ-CO)2(CO)16] (6). indenyl ligand compound 6 exhibits novel bonding mode which benzenoid ring is μ4,η1:η1:η2:η2 bound to cluster. Refluxing bis-indenyl methane [Ru2(CO)4{μ-(η5-C9H6)2CH2}] (7), reacts iodine via Ru–Ru bond cleavage give [Ru2I2(CO)4{(η5-C9H6)2CH2}] (8).
elsevier.com
sci-hub.se 参考文章(43)
O.S. Mills, J.P. Nice, Carbon compounds of the transition metals Journal of Organometallic Chemistry. ,vol. 9, pp. 339- 344 ,(1967) , 10.1016/S0022-328X(00)83735-3
R.B. King, M.Z. Iqbal, A.D. King, Pentamethylcyclopentadienyl derivatives of transition metals: VI. Carbonylation of metalmetal triple bonds: a high pressure infrared spectroscopic study Journal of Organometallic Chemistry. ,vol. 171, pp. 53- 63 ,(1979) , 10.1016/S0022-328X(00)88063-8
B. F. Hallam, P. L. Pauson, 126. Ferrocene derivatives. Part IV. Indenyl- and tetrahydro-indenyl-iron carbonyls Journal of the Chemical Society (Resumed). pp. 646- 650 ,(1958) , 10.1039/JR9580000646
Patricia Alvarez, Mauro Bassetti, José Gimeno, Giovanna Mancini, Hydration of terminal alkynes to aldehydes in aqueous micellar solutions by ruthenium(II) catalysis; first anti-Markovnikov addition of water to propargylic alcohols Tetrahedron Letters. ,vol. 42, pp. 8467- 8470 ,(2001) , 10.1016/S0040-4039(01)01841-X
Selby A. R. Knox, Kirsty A. Macpherson, A. Guy Orpen, Melvyn C. Rendle, Organic chemistry of dinuclear metal centres. Part 13. Synthesis, structure, and reactivity of [Ru2(CO)4(η5: η5′-C5H4CH2C5H4)] Journal of The Chemical Society-dalton Transactions. pp. 1807- 1813 ,(1989) , 10.1039/DT9890001807
Mark E. Rerek, Liang-Nian Ji, Fred Basolo, The indenyl ligand effect on the rate of substitution reactions of Rh(η-C9H7)(CO)2 and Mn(η-C9H7)(CO)3 Journal of The Chemical Society, Chemical Communications. pp. 1208- 1209 ,(1983) , 10.1039/C39830001208
M Stradiotto*, η1-Indenyl derivatives of transition metal and main group elements: synthesis, characterization and molecular dynamics Coordination Chemistry Reviews. ,vol. 219, pp. 311- 378 ,(2001) , 10.1016/S0010-8545(01)00339-3
Masami Kamigaito, Yasuhiro Watanabe, Tsuyoshi Ando, Mitsuo Sawamoto, A new ruthenium complex with an electron-donating aminoindenyl ligand for fast metal-mediated living radical polymerizations. Journal of the American Chemical Society. ,vol. 124, pp. 9994- 9995 ,(2002) , 10.1021/JA0270470
Oscar Tutusaus, Sébastien Delfosse, Albert Demonceau, Alfred F Noels, Rosario Núñez, Clara Viñas, Francesc Teixidor, Olefin cyclopropanation catalysed by half-sandwich ruthenium complexes Tetrahedron Letters. ,vol. 43, pp. 983- 987 ,(2002) , 10.1016/S0040-4039(01)02292-4
Maria José Calhorda, Vitor Félix, Luı́s F Veiros, Bonding and structural preferences of indenyl complexes: MInd2Ln (n=0–3) Coordination Chemistry Reviews. ,vol. 230, pp. 49- 64 ,(2002) , 10.1016/S0010-8545(02)00081-4