A dithioxo-bishydroxylaminomolybdenum complex as sulfur and nitrogen transfer reagent. Synthesis of thioureas from isonitriles

作者: Janice J. Byrne , Yannick Vallée

DOI: 10.1016/S0040-4039(98)02418-6

关键词:

摘要: Abstract Cis -dithioxo-bis(( N,N -diethyl)hydroxylamido(1-)- O,N )molydenum(VI) reacts with isonitriles to give the corresponding -diethylthioureas. A mechanism is proposed for this S,N-transfer reaction.

参考文章(11)
B. R. Brown, The organic chemistry of aliphatic nitrogen compounds Clarendon Press , Oxford University Press. ,(1994)
L. Keith Woo, J. Alan Hays, Victor G. Young, Catherine L. Day, Cecile Caron, Francis D'Souza, Karl M. Kadish, Synthesis, Characterization, Substitution, and Atom- Transfer Reactions of (ŋ2-Aikyne)(tetratolylporphyrinato)titanium(II). X-ray Structure of trans- Bis( 4-picoline) ( tetratolylporphyrinato )titanium(II) Inorganic Chemistry. ,vol. 32, pp. 4186- 4192 ,(1993) , 10.1021/IC00072A007
Takahiko Akiyama, Iwao Ojima, Catalytic Asymmetric Synthesis Accounts of Chemical Research. ,vol. 33, pp. 324- 324 ,(2000) , 10.1021/AR000046X
Torsten Linker, The Jacobsen–Katsuki Epoxidation and Its Controversial Mechanism Angewandte Chemie. ,vol. 36, pp. 2060- 2062 ,(1997) , 10.1002/ANIE.199720601
R. Guilard, C. Ratti, J. M. Barbe, D. Dubois, K. M. Kadish, Synthesis and characterization of tin(IV) porphyrins with sulfide and selenide axial ligands Inorganic Chemistry. ,vol. 30, pp. 1537- 1542 ,(1991) , 10.1021/IC00007A021
K. Wieghardt, M. Hahn, J. Weiss, W. Swiridoff, Hydroxylamido(1-)-O,N-Komplexe des Molybdäns(VI) mit terminalen Oxo-, Sulfido- und Selenido-Liganden Die Kristallstrukturen von [MoO2(C5H10NO)2] und von [MoS2(C5H10NO)2] Zeitschrift für anorganische und allgemeine Chemie. ,vol. 492, pp. 164- 174 ,(1982) , 10.1002/ZAAC.19824920119
Ahmad Q. Hussein, Johannes C. Jochims, Reaktionen von α-Bromisothiocyanaten Chemische Berichte. ,vol. 112, pp. 1956- 1972 ,(1979) , 10.1002/CBER.19791120606
David Britnell, Gerald W. A. Fowles, David A. Rice, Preparation of halide sulphides and halide selenides of molybdenum and tungsten Journal of the Chemical Society, Dalton Transactions. pp. 2191- 2194 ,(1974) , 10.1039/DT9740002191
Gerald W. A. Fowles, Richard J. Hobson, David A. Rice, Kenneth J. Shanton, Ambient temperature preparations of thio-, seleno-, and oxo-halides of niobium, tantalum, molybdenum, tungsten, and rhenium Journal of the Chemical Society, Chemical Communications. pp. 552b- ,(1976) , 10.1039/C3976000552B