Electrochemistry of lutetium crowned ether diphthalocyanine films
作者： M. Bardin , E. Bertounesque , V. Plichon , J. Simon , V. Ahsen
DOI: 10.1016/0022-0728(89)80073-7
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摘要: Films of crown-ether substituted diphthalocyanine lutetium (CR-Pc2Lu) have been studied by cyclic voltammetry. In contact with K+ or Na+ aqueous electrolyte, two reversible one-electron steps lead to the formation orange cation CR-Pc2Lu+ and blue anion CR-Pc2Lu−. With other alkali metal cations, irreversibility both increases in order K+, ⪡ Li+ < Rb+, Cs+. In acid medium (HCl HClO4), voltammetry cannot be performed absence added simultaneously solution, destruction films occurs. a KCl + HCl KClO4 HClO4 disproportionation CR-Pc2 Lu proceeds two-electron voltammetric peak takes place steps. A E-pH “Pourbaix” diagram is established.
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sci-hub.se 参考文章(13)
F. Castaneda, V. Plichon, Electrochemical process in electrochromic films of lutetium diphthalocyanine Journal of Electroanalytical Chemistry. ,vol. 236, pp. 163- 175 ,(1987) , 10.1016/0022-0728(87)88024-5
Ot E. Sielcken, Marcus M. Van Tilborg, Maarten F. M. Roks, Ron Hendriks, Wiendelt Drenth, Reoland J. M. Nolte, Synthesis and aggregation behavior of hosts containing phthalocyanine and crown ether subunits Journal of the American Chemical Society. ,vol. 109, pp. 4261- 4265 ,(1987) , 10.1021/JA00248A021
F. Castaneda, V. Plichon, C. Clarisse, M.T. Riou, Electrochemistry of a lutetium diphthalocyanine film in contact with an acidic aqueous medium Journal of Electroanalytical Chemistry. ,vol. 233, pp. 77- 85 ,(1987) , 10.1016/0022-0728(87)85007-6
S. Besbes, V. Plichon, J. Simon, J. Vaxiviere, Electrochromism of octaalkoxymethyl-substituted lutetium diphthalocyanine Journal of Electroanalytical Chemistry. ,vol. 237, pp. 61- 68 ,(1987) , 10.1016/0022-0728(87)80307-8
G. C. S. Collins, D. J. Schiffrin, The Properties of Electrochromic Film Electrodes of Lanthanide Diphthalocyanines in Ethylene Glycol Journal of The Electrochemical Society. ,vol. 132, pp. 1835- 1842 ,(1985) , 10.1149/1.2114227
Jean-Jacques Andre, Karol Holczer, Pierre Petit, Marie-Thérèse Riou, Christian Clarisse, Raymond Even, Marc Fourmigue, Jacques Simon, Electrical and magnetic properties of thin films and single crystals of bis(phthalocyaninato)lutetium Chemical Physics Letters. ,vol. 115, pp. 463- 466 ,(1985) , 10.1016/0009-2614(85)85171-X
Nagao Kobayashi, A. B. P. Lever, Cation or solvent-induced supermolecular phthalocyanine formation: crown ether substituted phthalocyanines Journal of the American Chemical Society. ,vol. 109, pp. 7433- 7441 ,(1987) , 10.1021/JA00258A030
Ali R. Koray, Vefa Ahsen, Özer Bekâroǧlu, Preparation of a novel, soluble copper phthalocyanine with crown ether moieties Journal of The Chemical Society, Chemical Communications. pp. 932- 933 ,(1986) , 10.1039/C39860000932
Vefa Ahsen, Emel Yilmazer, Mümtaz Ertas, Özer Bekâroğlu, Synthesis and characterization of metal-free and metal derivatives of a novel soluble crown-ether-containing phthalocyanine J. Chem. Soc., Dalton Trans.. pp. 401- 406 ,(1988) , 10.1039/DT9880000401
Ron Hendriks, Ot E. Sielcken, Wiendelt Drenth, Roeland J. M. Nolte, Polytopic ligand systems: synthesis and complexation properties of a ‘crowned’ phthalocyanine Journal of The Chemical Society, Chemical Communications. ,vol. 1986, pp. 1464- 1465 ,(1986) , 10.1039/C39860001464