Aliphatic poly(oxytetramethylene) ionenes: effect of counter-anion on the properties and morphology

作者: Yuko Ikeda , Jyunya Yamato , Takeshi Murakami , Kanji Kajiwara

DOI: 10.1016/J.POLYMER.2004.09.082

关键词:

摘要: Abstract Effect of counter-anion on the properties and morphology aliphatic poly(oxytetramethylene) ionenes was investigated, relationship between elucidated. The possess elastic at low elongations whereas they predominantly exhibit a plastic deformation high elongations. analysed in nanometer scale by fitting cascade model for randomly branched f -functional polycondensates incorporated Debye–Bueche random-two-phase interference term interdomain interaction their small-angle X-ray scattering profiles. size ionic domains distance were smaller shorter ionene with bromide than those chloride counter-anion, respectively. formation crystallite (POTM) segments detected room temperature. These characteristics POTM gave difference mechanical thermal properties.

参考文章(27)
D. McIntyre, F. Gornick, Light scattering from dilute polymer solutions Gordon and Breach Science. ,(1964)
Paul J. Flory, Principles of polymer chemistry ,(1953)
Frederick R. Eirich, Science and Technology of Rubber ,(2012)
S. N. Bagchi, R. Hosemann, Direct analysis of diffraction by matter North-Holland Pub. Co.. ,(1962)
Shinzo Kohjiya, Tohru Ohtsuki, Shinzo Yamashita, Polyelectrolyte behavior of an ionene containing poly(oxytetramethylene) units Die Makromolekulare Chemie, Rapid Communications. ,vol. 2, pp. 417- 420 ,(1981) , 10.1002/MARC.1981.030020611
Eric J. Goethals, Peter Van Caeter, Jan M. Geeraert, Filip E. Du Prez, Tailored polymers by cationic ring‐opening polymerization Angewandte Makromolekulare Chemie. ,vol. 223, pp. 1- 11 ,(1994) , 10.1002/APMC.1994.052230101
Shinzo Kohjiya, Tohru Ohtsuki, Shinzo Yamashita, Kinetic studies on the Menschutkin reaction of dimethylamino-terminated poly(oxytetramethylene) with halides Macromolecular Chemistry and Physics. ,vol. 191, pp. 397- 403 ,(1990) , 10.1002/MACP.1990.021910214