作者: Yuko Ikeda , Jyunya Yamato , Takeshi Murakami , Kanji Kajiwara
DOI: 10.1016/J.POLYMER.2004.09.082
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摘要: Abstract Effect of counter-anion on the properties and morphology aliphatic poly(oxytetramethylene) ionenes was investigated, relationship between elucidated. The possess elastic at low elongations whereas they predominantly exhibit a plastic deformation high elongations. analysed in nanometer scale by fitting cascade model for randomly branched f -functional polycondensates incorporated Debye–Bueche random-two-phase interference term interdomain interaction their small-angle X-ray scattering profiles. size ionic domains distance were smaller shorter ionene with bromide than those chloride counter-anion, respectively. formation crystallite (POTM) segments detected room temperature. These characteristics POTM gave difference mechanical thermal properties.