Electrochemical sensor for nitric oxide using layered films composed of a polycationic dendrimer and nickel(II) phthalocyaninetetrasulfonate deposited on a carbon fiber electrode

作者: Juliana Cancino , Sabine Borgmann , Sergio A. S. Machado , Valtencir Zucolotto , Wolfgang Schuhmann

DOI: 10.1007/S00604-014-1425-0

关键词:

摘要: We have developed an electrochemical sensor for nitric oxide that is based on multi-layers of nickel(II) phthalocyaninetetrasulfonate and a polyamidoamine dendrimer assembled the surface carbon-fiber microelectrode. This responds to at working potential 800 mV with sensitivity 5.54 pA∙μM‾1 which, however, depends layer position deposited The limit detection as low 5.5 μM signal-to-noise ratio 3. electrode exhibits good selectivity over common interferents including dopamine, nitrite, hydrogen peroxide, norepinephrine, epinephrine ascorbic acid.

参考文章(34)
Friedrich Wilhelm Küster, Alfred Thiel, Rechentafeln für die chemische Analytik De Gruyter. ,(1982) , 10.1515/9783111509631
M Biesaga, Porphyrins in analytical chemistry. A review Talanta. ,vol. 51, pp. 209- 224 ,(2000) , 10.1016/S0039-9140(99)00291-X
Jiye Jin, Tomoo Miwa, Lanqun Mao, Huiping Tu, Litong Jin, Determination of nitric oxide with ultramicrosensors based on electropolymerized films of metal tetraaminophthalocyanines Talanta. ,vol. 48, pp. 1005- 1011 ,(1999) , 10.1016/S0039-9140(98)00308-7
Maxime Pontié, Cédric Gobin, Thierry Pauporté, Féthi Bedioui, Jacques Devynck, Electrochemical nitric oxide microsensors: sensitivity and selectivity characterisation Analytica Chimica Acta. ,vol. 411, pp. 175- 185 ,(2000) , 10.1016/S0003-2670(00)00741-8
Sabine Borgmann, Electrochemical quantification of reactive oxygen and nitrogen: challenges and opportunities Analytical and Bioanalytical Chemistry. ,vol. 394, pp. 95- 105 ,(2009) , 10.1007/S00216-009-2692-1
Frank Marken, John C. Eklund, Richard G. Compton, Voltammetry in the presence of ultrasound: Can ultrasound modify heterogeneous electron transfer kinetics? Journal of Electroanalytical Chemistry. ,vol. 395, pp. 335- 339 ,(1995) , 10.1016/0022-0728(95)04268-S
Tsai-Mu Cheng, Tzu-Cheng Lee, Shin-Hua Tseng, Hsueh-Liang Chu, Ju-Pin Pan, Chia-Ching Chang, Human haptoglobin phenotypes and concentration determination by nanogold-enhanced electrochemical impedance spectroscopy Nanotechnology. ,vol. 22, pp. 245105- ,(2011) , 10.1088/0957-4484/22/24/245105