On the origin of product selectivity in aqueous diels-alder reactions

作者: Ronald Breslow , Uday Maitra

DOI: 10.1016/S0040-4039(01)80122-2

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摘要: … is soluble in water at 10 rnx, so we have examined the products of reaction at room temperature with 10 rn! methyl vinyl ketone over a cyclopentadiene … state is at least part of the …

参考文章(3)
Darryl C. Rideout, Ronald Breslow, Hydrophobic acceleration of Diels-Alder reactions Journal of the American Chemical Society. ,vol. 102, pp. 7816- 7817 ,(1980) , 10.1021/JA00546A048
Ronald Breslow, Uday Maitra, Darryl Rideout, Selective diels-alder reactions in aqueous solutions and suspensions Tetrahedron Letters. ,vol. 24, pp. 1901- 1904 ,(1983) , 10.1016/S0040-4039(00)81801-8
Paul A. Grieco, Philip Garner, Zhen-min He, “Micellar” catalysis in the aqueous intermolecular diels-alder reaction: rate acceleration and enhanced selectivity Tetrahedron Letters. ,vol. 24, pp. 1897- 1900 ,(1983) , 10.1016/S0040-4039(00)81800-6