Enhanced Catalytic Reduction of 4-Nitrophenol Driven by Fe₃O₄-Au Magnetic Nanocomposite Interface Engineering: From Facile Preparation to Recyclable Application.

作者: Yue Chen , Yuanyuan Zhang , Qiangwei Kou , Yang Liu , Donglai Han

DOI: 10.3390/NANO8050353

关键词:

摘要: In this work, we report the enhanced catalytic reduction of 4-nitrophenol driven by Fe3O4-Au magnetic nanocomposite interface engineering. A facile solvothermal method is employed for Fe3O4 hollow microspheres and synthesis via a seed deposition process. Complementary structural, chemical composition valence state studies validate that as-obtained samples are formed in pure magnetite phase. series characterizations including conventional scanning/transmission electron microscopy (SEM/TEM), Mossbauer spectroscopy, testing elemental mapping conducted to unveil structural physical characteristics developed nanocomposites. By adjusting quantity Au seeds coating on polyethyleneimine-dithiocarbamates (PEI-DTC)-modified surfaces microspheres, correlation between amount ability nanocomposites (4-NP) investigated systematically. Importantly, bearing remarkable recyclable features, our can be readily separated with magnet. Such shine light highly efficient catalysts 4-NP at mass production level.

参考文章(93)
I. Kazeminezhad, S. Mosivand, Phase Transition of Electrooxidized Fe_3O_4 to γ and α-Fe_2O_3 Nanoparticles Using Sintering Treatment Acta Physica Polonica A. ,vol. 125, pp. 1210- 1214 ,(2014) , 10.12693/APHYSPOLA.125.1210
Xiao Zhang, Li Song, Le Cai, Xuezeng Tian, Qiang Zhang, Xiaoying Qi, Wenbin Zhou, Nan Zhang, Feng Yang, Qingxia Fan, Yanchun Wang, Huaping Liu, Xuedong Bai, Weiya Zhou, Sishen Xie, None, Optical visualization and polarized light absorption of the single-wall carbon nanotube to verify intrinsic thermal applications Light-Science & Applications. ,vol. 4, ,(2015) , 10.1038/LSA.2015.91
Wang, Jin Luo, Quan Fan, Masatsugu Suzuki, Itsuko S Suzuki, Mark H Engelhard, Yuehe Lin, Nam Kim, Jian Q Wang, Chuan-Jian Zhong, None, Monodispersed core-shell Fe3O4@Au nanoparticles. Journal of Physical Chemistry B. ,vol. 109, pp. 21593- 21601 ,(2005) , 10.1021/JP0543429
Zhendong Zhu, Benfeng Bai, Oubo You, Qunqing Li, Shoushan Fan, Fano resonance boosted cascaded optical field enhancement in a plasmonic nanoparticle-in-cavity nanoantenna array and its SERS application Light-Science & Applications. ,vol. 4, ,(2015) , 10.1038/LSA.2015.69
Min Ye, Zewen Wei, Fei Hu, Jianxin Wang, Guanglu Ge, Zhiyuan Hu, Mingwang Shao, Shuit-Tong Lee, Jian Liu, Fast assembling microarrays of superparamagnetic Fe3O4@Au nanoparticle clusters as reproducible substrates for surface-enhanced Raman scattering. Nanoscale. ,vol. 7, pp. 13427- 13437 ,(2015) , 10.1039/C5NR02491A
Yong Hu, Jia Yang, Ping Wei, Jingchao Li, Ling Ding, Guixiang Zhang, Xiangyang Shi, Mingwu Shen, Facile synthesis of hyaluronic acid-modified Fe3O4/Au composite nanoparticles for targeted dual mode MR/CT imaging of tumors Journal of Materials Chemistry B. ,vol. 3, pp. 9098- 9108 ,(2015) , 10.1039/C5TB02040A
Chongwen Wang, Ping Li, Junfeng Wang, Zhen Rong, Yuanfeng Pang, Jiawen Xu, Peitao Dong, Rui Xiao, Shengqi Wang, Polyethylenimine-interlayered core–shell–satellite 3D magnetic microspheres as versatile SERS substrates Nanoscale. ,vol. 7, pp. 18694- 18707 ,(2015) , 10.1039/C5NR04977F
Runa Ghosh, Lina Pradhan, Yensenbam Priyabala Devi, SS Meena, R Tewari, Amit Kumar, Sachil Sharma, NS Gajbhiye, RK Vatsa, Badri N Pandey, RS Ningthoujam, None, Induction heating studies of Fe3O4 magnetic nanoparticles capped with oleic acid and polyethylene glycol for hyperthermia Journal of Materials Chemistry. ,vol. 21, pp. 13388- 13398 ,(2011) , 10.1039/C1JM10092K
Benyang Wang, Shiliang Qu, Absorption spectra and near-electric field enhancement effects of Au- and Ag-Fe3O4 dimers Applied Surface Science. ,vol. 292, pp. 1002- 1008 ,(2014) , 10.1016/J.APSUSC.2013.12.103