Assessment of using Carbon Soot as economic adsorbing material for the removal of cobalt(II) from aqueous solution

作者: Mohamed I. Attia

DOI: 10.3233/MGC-140147

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摘要: In this work, the removal of cobalt ions from aqueous solutions by carbon soot which is a very cheap industrial by-product has been studied. Its objective was to investigate possibility using instead high cost commercial adsorbent materials for solution. Different adsorption isotherms (Langmuir, Freundlich, and Brauner-Emmett-Teller) were applied. The rate constant (Kad), intraparticle diffusion (Kp), pore coefficient (D), overall reaction (K), equilibrium (Kc), activation energy (E) thermodynamic functionsG ◦ , � H andS estimated. Also effect time, sorbent dose, initial concentration pH at different temperatures results interesting, indicating that capable removing cobalt(II) an time on larger than powdered activated carbon. Cobalt dependent. kinetics investigated as first order controlled spontaneous process.

参考文章(32)
E. A. Sigworth, S. B. Smith, Adsorption of Inorganic Compounds by Activated Carbon Journal - American Water Works Association. ,vol. 64, pp. 386- 391 ,(1972) , 10.1002/J.1551-8833.1972.TB02713.X
Cecile N. Hurley, William L. Masterson, Chemistry : principles & reactions Saunders College. ,(1989)
I. M. Kolthoff, E. B. Sandell, Philip Juliber Elving, Analytical chemistry of the elements Interscience. ,(1961)
I.B. Rae, S.W. Gibb, Removal of metals from aqueous solutions using natural chitinous materials. Water Science and Technology. ,vol. 47, pp. 189- 196 ,(2003) , 10.2166/WST.2003.0572
I. M. Kolthoff, E. B. Sandell, Textbook of quantitative inorganic analysis ,(1948)
John Crank, The mathematics of diffusion ,(1956)
C. Gómez-Lahoz, F. García-Herruzo, J.M. Rodríguez-Maroto, J.J. Rodríguez, Cobalt(II) removal from water by chemical reduction with sodium borohydride Water Research. ,vol. 27, pp. 985- 992 ,(1993) , 10.1016/0043-1354(93)90062-M
A Netzer, Adsorption of copper, lead and cobalt by activated carbon Water Research. ,vol. 18, pp. 927- 933 ,(1984) , 10.1016/0043-1354(84)90241-0
Asit K. Sen, Arnab K. De, Adsorption of mercury(II) by coal fly ash Water Research. ,vol. 21, pp. 885- 888 ,(1987) , 10.1016/S0043-1354(87)80003-9