Allyl Ligand Reactivity in Tantalum(V) Compounds: Experimental and Computational Evidence for Allyl Transfer to the Formamidinate Ligand in fac-Ta(NMe2)3(η1-allyl)[iPrNC(H)NiPr] via a Metallo-Claisen Rearrangement
作者： Shih-Huang Huang , Xiaoping Wang , Vladimir Nesterov , David A. Hrovat , Michael B. Hall
DOI: 10.1021/OM200683Q
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摘要: Treatment of TaCl(NMe2)4 (1) with allylMgCl furnishes the allyl-substituted compound Ta(NMe2)4(η1-allyl) (2) in moderate yield. The X-ray structure 2 reveals a trigonal-bipyramidal geometry at t...
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