Photodissociation of O2 at 157 nm: Experimental observation of anisotropy mixing in the O2+hν→O(3P)+O(3P) channel

摘要: In this work, photodissociation of O2 at 157 nm has been studied using the photofragmentation translational spectroscopic technique. Two product channels O2+hν→O(1D)+O(3P), O2+hν→O(3P)+O(3P) have observed. The relative yields and anisotropy parameters both are determined. Anisotropy mixing dissociation resulting from a perpendicular excitation parallel-type observed in channel O2+hν→O(3P)+O(3P). results can be used to look detailed dynamical processes through Schumann–Runge band.