Oxidation of palladium(I) dimers: Formation and X-ray crystal structure of [(Me3P)2Pd(μ-OH)2Pd(PMe3)2](CF3SO3)2
作者： Giuseppe Pieri , Marco Pasquali , Piero Leoni , Ulli Englert
DOI: 10.1016/0022-328X(94)05233-2
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摘要: Abstract Air oxidation of the phosphido-bridged Pd(I) dimer Pd2(μ-PtBu2)(PMe3)4]CF3SO3) gives hydroxo-bridged Pd(II) dinuclear derivative [(ME3P)2Pd(μ-OH)2Pd(PMe2)2](CF3SO2 (1) with a low yield. The same cation was obtained high yield by reaction [PdCl2(PMe3)2] silver nitrate in wet acetone. crystal structure 1 determined.
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